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Concentrations and Seasonal Variation of Ambient PM2.5 and Associated Metals at a Typical Residential Area in Beijing, China

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Abstract

In this study, continuous monitoring of PM2.5 was carried out for 1 year period at one of the largest residential areas in Beijing. Annual mean of PM2.5 during sampling period was 100.4 µg/m3. The seasonal variation trend of PM2.5 was winter > spring > autumn and summer. The total mass concentrations of metals in PM2.5 ranged from 0.4 to 13.2 μg/m3. There were significant (p < 0.05) seasonal variations for concentrations of Ca, Al, Mn, As, Rb, Cr, Ni, Cd and Co, seasonal variations in PM-associated metals were not necessarily the same as the seasonal variation in PM2.5, related to differing seasonal trends in source types. The impact of meteorological factors (e.g., wind speed) on metals levels of PM2.5 was found to be significant by regression models. The EFs value of Ag, Ca, Cd, Pb, Zn, As, Cu, and Cr were higher than ten, suggesting that those elements were primarily contributed by anthropogenic sources. Seasonal characteristic of EFs were found for As, Cr, Ca and Ag, which indicating the seasonal pollution sources types for those metals. Overall, these findings indicated that the pollution control of ambient PM2.5 should not be negligible in residential area in Beijing and the local government should pertinent and accurate prevent and control of air pollution as well as protect human health.

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Abbreviations

PM:

Atmospheric particulate matters

PM10 :

The coarse PM, aerodynamic diameter of particle ≤10 µm

PM2.5 :

The fine PM, aerodynamic diameter of particle ≤2.5 µm

RH:

Relative humanity

EF:

Enrichment factor

NAAQS:

National ambient air quality standard

References

  • Calvo AI et al (2008) Chemical composition of urban aerosols in Toulouse France during CAPITOUL experiment. Meteorol Atmos Phys 102:307–323. doi:10.1007/s00703-008-0319-2

    Article  Google Scholar 

  • Cao JJ et al (2012) Winter and summer PM2.5 chemical compositions in fourteen Chinese cities. J Air Waste Manag Assoc 62:1214–1226

    Article  CAS  Google Scholar 

  • Chan CK, Yao X (2008) Air pollution in mega cities in China. Atmos Environ 42:1–42. doi:10.1016/j.atmosenv.2007.09.003

    Article  CAS  Google Scholar 

  • Chandra Mouli P, Venkata Mohan S, Balaram V, Praveen Kumar M, Jayarama Reddy S (2006) A study on trace elemental composition of atmospheric aerosols at a semi-arid urban site using ICP-MS technique. Atmos Environ 40:136–146. doi:10.1016/j.atmosenv.2005.09.028

    Article  CAS  Google Scholar 

  • Chillrud SN, Epstein D, Ross JM, Sax SN, Pederson D, Spengler JD, Kinney PL (2003) Elevated airborne exposures of teenagers to manganese chromium, and iron from steel dust and New York City’s subway system. Environ Sci Technol 38:732–737. doi:10.1021/es034734y

    Article  Google Scholar 

  • Deng J, Wang T, Jiang Z, Xie M, Zhang R, Huang X, Zhu J (2011) Characterization of visibility and its affecting factors over Nanjing, China. Atmos Res 101:681–691. doi:10.1016/j.atmosres.2011.04.016

    Article  CAS  Google Scholar 

  • Duan J, Tan J (2013) Atmospheric heavy metals and arsenic in China: situation, sources and control policies. Atmos Environ 74:93–101. doi:10.1016/j.atmosenv.2013.03.031

    Article  CAS  Google Scholar 

  • Duan FK, Liu XD, He KB, Lu YQ, Wang L (2003) Atmospheric aerosol concentration level and chemical characteristics of water-soluble ionic species in wintertime in Beijing, China. J Environ Monit 5:569–573. doi:10.1039/B303691J

    Article  CAS  Google Scholar 

  • Duan J, Tan J, Hao J, Chai F (2014) Size distribution, characteristics and sources of heavy metals in haze episod in Beijing. J Environ Sci 26:189–196. doi:10.1016/S1001-0742(13)60397-6

    Article  CAS  Google Scholar 

  • Fang G-C, Huang Y-L, Huang J-H (2010) Study of atmospheric metallic elements pollution in Asia during 2000–2007. J Hazard Mater 180:115–121. doi:10.1016/j.jhazmat.2010.03.120

    Article  CAS  Google Scholar 

  • Feng J, Chan CK, Fang M, Hu M, He L, Tang X (2005) Impact of meteorology and energy structure on solvent extractable organic compounds of PM2.5 in Beijing, China. Chemosphere 61:623–632. doi:10.1016/j.chemosphere.2005.03.067

    Article  CAS  Google Scholar 

  • Ge S et al (2004) Emissions of air pollutants from household stoves: honeycomb coal versus coal cake. Environ Sci Technol 38:4612–4618. doi:10.1021/es049942k

    Article  CAS  Google Scholar 

  • Guo S, Tan J, Duan J, Ma Y, Yang F, He K, Hao J (2012) Characteristics of atmospheric non-methane hydrocarbons during haze episode in Beijing, China. Environ Monit Assess 184:7235–7246. doi:10.1007/s10661-011-2493-9

    Article  CAS  Google Scholar 

  • Han B et al (2010) Characterization of elemental species in PM2.5 samples collected in four cities of Northeast China. Water Air Soil Pollut 209:15–28. doi:10.1007/s11270-009-0176-8

    Article  CAS  Google Scholar 

  • Hu H, Yang Q, Lu X, Wang W, Wang S, Fan M (2010) Air pollution and control in different areas of China. Crit Rev Environ Sci Technol 40:452–518. doi:10.1080/10643380802451946

    Article  Google Scholar 

  • Karar K, Gupta AK (2006) Seasonal variations and chemical characterization of ambient PM10 at residential and industrial sites of an urban region of Kolkata (Calcutta), India. Atmos Res 81:36–53. doi:10.1016/j.atmosres.2005.11.003

    Article  CAS  Google Scholar 

  • Kauppinen EI, Pakkanen TA (1990) Coal combustion aerosols: a field study. Environ Sci Technol 24:1811–1818. doi:10.1021/es00082a004

    Article  CAS  Google Scholar 

  • Kim K-H, Choi G-H, Kang C-H, Lee J-H, Kim JY, Youn YH, Lee SR (2003) The chemical composition of fine and coarse particles in relation with the Asian Dust events. Atmos Environ 37:753–765. doi:10.1016/S1352-2310(02)00954-8

    Article  CAS  Google Scholar 

  • Kolker A, Engle MA, Peucker-Ehrenbrink B, Geboy NJ, Krabbenhoft DP, Bothner MH, Tate MT (2013) Atmospheric mercury and fine particulate matter in coastal New England: Implications for mercury and trace element sources in the northeastern United States. Atmos Environ 79:760–768. doi:10.1016/j.atmosenv.2013.07.031

    Article  CAS  Google Scholar 

  • Kothai P, Saradhi IV, Prathibha P, Pandit GG, Puranik VD (2012) Concentration levels and temporal variations of heavy elements in the urban particulate matter of Navi Mumbai, India. J Radioanal Nucl Chem 294:453–459. doi:10.1007/s10967-011-1502-3

    Article  CAS  Google Scholar 

  • Li X, Wang Y, Guo X, Wang Y (2013) Seasonal variation and source apportionment of organic and inorganic compounds in PM2.5 and PM10 particulates in Beijing, China. J Environ Sci 25:741–750. doi:10.1016/S1001-0742(12)60121-1

    Article  CAS  Google Scholar 

  • Liu G, Li J, Wu D, Xu H (2014) Chemical composition and source apportionment of the ambient PM2.5 in Hangzhou, China. Particuology. doi:10.1016/j.partic.2014.03.011

    Google Scholar 

  • Marcazzan GM, Valli G, Vecchi R (2002) Factors influencing mass concentration and chemical composition of fine aerosols during a PM high pollution episode. Sci Total Environ 298:65–79. doi:10.1016/S0048-9697(02)00171-7

    Article  CAS  Google Scholar 

  • Martuzevicius D et al (2004) Spatial and temporal variations of PM2.5 concentration and composition throughout an urban area with high freeway density—the Greater Cincinnati study. Atmos Environ 38:1091–1105. doi:10.1016/j.atmosenv.2003.11.015

    Article  CAS  Google Scholar 

  • MEP (2011) Determination of atmospheric articles PM10 and PM2.5 in ambient air by gravimetric method, GB 618-2011

  • MEP (2012) Ambient air quality standards, GB 3095-2012

  • Muschack W (1990) Pollution of street run-off by traffic and local conditions. Sci Total Environ 93:419–431. doi:10.1016/0048-9697(90)90133-F

    Article  CAS  Google Scholar 

  • Oberdorster G, Oberdorster E, Oberdorster J (2005) Nanotoxicology: an emerging discipline evolving from studies of ultrafine particles. Environ Health Perspect 113:823–839

    Article  CAS  Google Scholar 

  • Okuda T et al (2008) Trends in hazardous trace metal concentrations in aerosols collected in Beijing, China from 2001 to 2006. Chemosphere 72:917–924. doi:10.1016/j.chemosphere.2008.03.033

    Article  CAS  Google Scholar 

  • Rogula-Kozłowska W et al (2013) PM2.5 in the central part of Upper Silesia, Poland: concentrations, elemental composition, and mobility of components. Environ Monit Assess 185:581–601. doi:10.1007/s10661-012-2577-1

    Article  Google Scholar 

  • Saldarriaga-Norena H, Hernandez-Mena L, Ramirez-Muniz M, Carbajal-Romero P, Cosio-Ramirez R, Esquivel-Hernandez B (2009) Characterization of trace metals of risk to human health in airborne particulate matter (PM2.5) at two sites in Guadalajara, Mexico. J Environ Monitor 11:887–894. doi:10.1039/B815747B

  • Schleicher N, Norra S, Chai F, Chen Y, Wang S, Stüben D (2010) Seasonal trend of water-soluble ions at one TSP and five PM2.5 sampling sites in Beijing, China. In: Rauch S, Morrison GM, Monzón A (eds) Highway and urban environment, 17th edn. Springer, Netherlands, pp 87–95. doi:10.1007/978-90-481-3043-6_10

    Google Scholar 

  • Schleicher N, Cen K, Norra S (2013) Daily variations of black carbon and element concentrations of atmospheric particles in the Beijing megacity—Part 1: general temporal course and source identification. Chemie der Erde Geochem 73:51–60. doi:10.1016/j.chemer.2012.11.006

    Article  CAS  Google Scholar 

  • Song S, Wu Y, Jiang J, Yang L, Cheng Y, Hao J (2012) Chemical characteristics of size-resolved PM2.5 at a roadside environment in Beijing, China. Environ Pollut 161:215–221. doi:10.1016/j.envpol.2011.10.014

    Article  CAS  Google Scholar 

  • Statistical bulletin for national economic and social development (2012) National Bureau of statistics of China. www.statsgovcn/tjgb/ndtjgb/qgndtjgb/t20130221_402874525htm

  • Sun Y, Zhuang G, Tang A, Wang Y, An Z (2006) Chemical characteristics of PM2.5 and PM10 in haze−fog episodes in Beijing. Environ Sci Technol 40:3148–3155. doi:10.1021/es051533g

    Article  CAS  Google Scholar 

  • Taylor SR, McLennan SM (1985) The continental crust: its composition and evolution. Blackwell, London, pp 57–72

  • Tian HZ, Wang Y, Xue ZG, Cheng K, Qu YP, Chai FH, Hao JM (2010) Trend and characteristics of atmospheric emissions of Hg, As, and Se from coal combustion in China, 1980–2007. Atmos Chem Phys 10:11905–11919. doi:10.5194/acp-10-11905-2010

    Article  CAS  Google Scholar 

  • Tian H, Wang Y, Xue Z, Qu Y, Chai F, Hao J (2011) Atmospheric emissions estimation of Hg, As, and Se from coal-fired power plants in China, 2007. Sci Total Environ 409:3078–3081. doi:10.1016/j.scitotenv.2011.04.039

    Article  CAS  Google Scholar 

  • Wang G, Kawamura K, Lee S, Ho K, Cao J (2006a) Molecular seasonal, and spatial distributions of organic aerosols from fourteen Chinese cities. Environ Sci Technol 40:4619–4625. doi:10.1021/es060291x

    Article  CAS  Google Scholar 

  • Wang Y, Zhuang G, Sun Y, An Z (2006b) The variation of characteristics and formation mechanisms of aerosols in dust, haze, and clear days in Beijing. Atmos Environ 40:6579–6591. doi:10.1016/j.atmosenv.2006.05.066

    Article  CAS  Google Scholar 

  • Weast RC (1969) Handbook of chemistry and physics, 49th ed. Am J Med Sci 257:423

    Article  Google Scholar 

  • Wu Y-S, Fang G-C, Lee W-J, Lee J-F, Chang C-C, Lee C-Z (2007) A review of atmospheric fine particulate matter and its associated trace metal pollutants in Asian countries during the period 1995–2005. J Hazard Mater 143:511–515. doi:10.1016/j.jhazmat.2006.09.066

    Article  CAS  Google Scholar 

  • Xia L, Gao Y (2011) Characterization of trace elements in PM2.5 aerosols in the vicinity of highways in northeast New Jersey in the US east coast. Atmos Pollut Res 2:34–44. doi:10.5094/APR.2011.005

  • Xu L, Chen X, Chen J, Zhang F, He C, Zhao J, Yin L (2012) Seasonal variations and chemical compositions of PM2.5 aerosol in the urban area of Fuzhou, China. Atmos Res 104–105:264–272. doi:10.1016/j.atmosres.2011.10.017

    Article  Google Scholar 

  • Yang H et al (2005) The chemical composition of inorganic and carbonaceous materials in PM2.5 in Nanjing, China. Atmos Environ 39:3735–3749. doi:10.1016/j.atmosenv.2005.03.010

    Article  CAS  Google Scholar 

  • Yu Y et al (2011) Dynamics and origin of PM2.5 during a three-year sampling period in Beijing, China. J Environ Monit JEM 13:334–346. doi:10.1039/c0em00467g

    Article  CAS  Google Scholar 

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Acknowledgments

The authors wish to express gratitude to everyone’s kind help in the preparation of this manuscript. This work was carried out under supported from grants GYHY201409011.

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Correspondence to Yeyao Wang.

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Yang, J., Fu, Q., Guo, X. et al. Concentrations and Seasonal Variation of Ambient PM2.5 and Associated Metals at a Typical Residential Area in Beijing, China. Bull Environ Contam Toxicol 94, 232–239 (2015). https://doi.org/10.1007/s00128-014-1443-y

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  • DOI: https://doi.org/10.1007/s00128-014-1443-y

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