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Molecular structural coefficients of Takács. Their dependence on column temperature, stationary phase polarity and solute chemical nature

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Summary

Molecular structural coefficients, Sc, for one hundred solutes have been calculated by means of the Takács equation using retention data obtained with over fifty stationary phases, SP. Employing data of seven SP's (characterized in our laboratories) it was found that the variation of Sc with column temperature was linear for most solutes. With data of n-decane and the ten McReynolds probes on up to fifty SP's of polarity less than RP=72, at 120°C, it was found that the Sc of n-decane and cis-hydrindane decreased slightly with increasing SP polarity, while the Sc of non-alkanes remained constant or increased very little as the SP polarity increased. The points for n-decane fit well to a second order polynomial. Again using a temperature of 120°C, the increments of Sc for solutes belonging to an homologous series were correlated with the polarity of SP's. Reasonably straight lines were obtained for all the chemical functions studied, Sc increasing with increasing SP polarity.

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  1. Instituto de Química Física Rocasolano, C.S.I.C., C/Serrano, 119, 28006, Madrid, Spain

    J. M. Santiuste

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Santiuste, J.M. Molecular structural coefficients of Takács. Their dependence on column temperature, stationary phase polarity and solute chemical nature. Chromatographia 38, 701–708 (1994). https://doi.org/10.1007/BF02269624

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