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Crystal structure of tris-(2,2′,2″)-triaminoethylamino-salicylidene iron(III) complex

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Abstract

Tris-(2,2′,2″)-triaminoethylamino-salicylidene iron(III) crystallizes in the monoclinic crystal system witha=7.766(2),b=25.423(5),c=13.318(5) Å, β=118.04(3)°, space group P21/c,V=2320.8(6) Å3,Z=4, andD x=1.464 g cm−3. The center of the axially distorted octahedron is occupied by the Fe atom which is coordinated by six donor nitrogen and oxygen atoms infac positions. The planes of coordinated atoms (N and O) with the Fe(III) atom are almost planar and the maximum elevated atom from these planes is O(1) (−0.1065 Å).

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Authors and Affiliations

  1. Department of Physics Engineering, Faculty of Sciences, University of Ankara, 06100, Besevler Ankara, Turkey

    Yalçin Elerman & Mehmet Kabak

  2. Strukturforschung, FB Materialwissenschaft Technische Hoshschule Darmstadt, Petersenstr. 20, 64287, Darmstadt, Germany

    Ingrid Svoboda & Hartmut Fuess

  3. Department of Chemistry, Faculty of Sciences, University of Ankara, 06100, Besevler Ankara, Turkey

    Orhan Atakol

Authors
  1. Yalçin Elerman
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  2. Mehmet Kabak
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  3. Ingrid Svoboda
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  4. Hartmut Fuess
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  5. Orhan Atakol
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Elerman, Y., Kabak, M., Svoboda, I. et al. Crystal structure of tris-(2,2′,2″)-triaminoethylamino-salicylidene iron(III) complex. J Chem Crystallogr 25, 227–230 (1995). https://doi.org/10.1007/BF01665174

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  • DOI: https://doi.org/10.1007/BF01665174

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