Abstract
In this work; (a) complexation reaction of zirconium tetra-n-butylate, Zr(OBun)4, with MAc and different organic acids. (b) the hydrolysis reaction of modified Zr species, and (c) the polymerization reaction of complex products are studied. Zr(OBun)4 was reacted with different mole ratios of methacrylic acid (MAc) at room temperature and the maximum combination ratio was found to be 1∶2 [Zr(OBun)4∶MAc] by FT IR. The modification of zirconium tetra-n-butylate with the acid mixtures [methacrylic acid-acetic acid (MeCOOH), methacrylic acid-propionic acid (EtCOOH), methacrylic acidbutyric acid (PrCOOH)] was made for a combination ratio of 1∶1∶1 [MAc∶RCOOH∶Zr(OBun)4∶R∶Me. Et, Pr] and the products were characterized by1H-NMR, FT-IR, and UV-spectroscopies. Following their synthesis, hydrolysis of the complexes with various amounts of water and polymerization with benzoyl peroxide were realized. The hydrolysis and polymerization products of the complexes were studied by Karl-Fischer Coulometric titration and thermal analysis respectively. Methyl-ethyl-ketone (MEK) and chloroform were chosen as solvents.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
F. Ribot, P. Toledano, and C. Sanchez,Chem. Mater. 3, 759 (1991).
M. Nabavi, S. Doeuff, C. Sanchez, and J. Livage,J. Non-Cyst. Solids 121, 31 (1990).
H. Schmidt,J. Non-Cryst. Solids 100, 51 (1988).
D. R. Ulrich,J. Non-Cryst. Solids 100, 174 (1988).
R. Nass, H. Schmidt, and E. Arpac,Sol-Gel Optics 1328, 258 (1990).
C. J. Brinker and G. W. Scherrer,Sol-Gel Science: The Physics and Chemistry of Sol-Gel Processing (Academic Press, New York, 1990).
M. J. Munoz-Aguado, M. Gregorkiewitz, and A. Larbot,Mater. Res. Bull. 27, 87 (1992).
J. Wenzel,J. Non-Cryst. Solids 73, 693 (1985).
S. Sakka,Am. Ceram. Soc. Bull. 63, 1136 (1984).
C. W. Hsieh, A. S. T. Chrang, C. C. Lee, and S. J. Yang,J. Non-Cryst. Solids 144, 53 (1992).
K. Yamada, T. Y. Chow, T. Horihata, and M. Nagata,J. Non-Cryst. Solids 100, 316 (1988).
C. Chen, D. F. Ryder, and W. A. Spurgeon,J. Am. Ceram. Soc. 72, 1495 (1989).
S. Sakka, H. Kozuka, and T. Umeda,Scramikkusu Ronbunshi 96, 468 (1988).
H. Nasu, M. Syoyama, and K. Kamiya,Jpn. J. Appl. Phys. 29, L1819 (1990).
G. Phillip and H. Schmidt,J. Non-Cryst. Solids 63, 283 (1984).
C. J. Brinker, D. E. Clarek, and D. R. Ulrich, eds.,Better Ceramics Through Chemistry (Elsevier, New York, 1984).
C. J. Brinker, D. E. Clarck, and D. R. Ulrich, eds.,Better Ceramics Through Chemistry (Elsevier, New York, 1986).
T. Hashimoto, K. Kamiya, and H. Nasu,J. Non-Cryst. Solids 143, 31 (1992).
M. L. Calzada and L. Del Olma,J. Non-Cryst. Solids 121, 413 (1990).
F. Babonneau, L. Coury, and J. Livage,J. Non-Cryst. Solids 121, 153 (1990).
M. Guglielmi and G. Carturan,J. Non-Cryst. Solids 100, 16 (1988).
C. Sanchez, J. Livage, M. Henry, and F. Babonneau,J. Non-Cryst. Solids 100, 65 (1988).
D. C. Bradley,Coord. Chem. Rev. 2, 299 (1967).
R. C. Menrotra,J. Non-Cryst. Solids 121, 1 6 (1990).
M. Guglielmi and G. Carturan,J. Non-Cryst. Solids 100, 24 (1988).
J. M. Mackenzie and D. R. Ulrich, eds.,Ultrastructure Processing of Advanced Ceramics (New York, 1988), p. 77.
V. K. H. Thiele und M. Panse,Z- Anorg. all. Chem 144, 23 (1978).
H. Saylikan, Applications of Sol-Gel Processing to Some Ti, Zr, and Al Alcoholates and Structural Analysis of the Products, PhD thesis, Inönü University, Malatya. Turkey (1992).
R. C. Mehrotra,J. Non-Cryst. Solids 100, 10 (1988).
S. Doeuff, M. Henry, C. Sanchez, and J. Livage,J. Non-Cryst. Solids 89, 206 216 (1987).
C. Sanchez and J. Livage,New J. Chem. 14, 513 (1990).
C. J. Brinker,J. Non-Cryst. Solids 100, 40 (1988).
J. C. Debsikdar,J. Non-Cryst. Solids 86, 231 (1986).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Sayilkan, H., Şener, Ş. & Arpaç, E. Zirconium tetra-n-butylate modified with different organic acids: Hydrolysis and polymerization of the products. J Inorg Organomet Polym 5, 409–423 (1995). https://doi.org/10.1007/BF01193063
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1007/BF01193063