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A water-soluble poly(methylphenylsilylene) derivative as a photoinitiator of radical polymerization of hydrophilic vinyl monomers

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Summary

Radicals formed during photoscission of the pyridinium salt of partially chloromethylated poly(methylphenysilylene) (Q-PMPSi) in aqueous solution are capable of initiating the polymerization of hydrophilic vinyl monomers, e.g. acrylic and methacrylic acid, acrylamide, 2-hydroxyethyl methacrylate and 1-vinyl-2-pyrrolidone.

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References

  1. R.Miller, J.Michl, Chem.Rev. 89, 1359 (1989).

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  2. R.West, A.R.Wolf, D.J.Peterson, J.Rad.Curing, 35, (1986).

  3. I.Kminek, E.Brynda, W.Schnabel, Eur.Polym.J., 27, 1073 (1991).

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Authors and Affiliations

  1. Institute of Macromolecular Chemistry, Czechoslovak Academy of Sciences, Heyrovsky Sq. 2, CS-16206, Prague 6, Czechoslovakia

    Ivan Kminek

  2. Department of Chemistry, Istanbul Technical University, Maslak, TR-80626, Istanbul, Turkey

    Yusuf Yagci

  3. Hahn-Meitner-Institute, Berlin GmbH, Bereich Photochemische Energieumwandlung, W-1000, Berlin 39, Federal Republic of Germany

    Wolfram Schnabel

Authors
  1. Ivan Kminek
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  2. Yusuf Yagci
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  3. Wolfram Schnabel
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Kminek, I., Yagci, Y. & Schnabel, W. A water-soluble poly(methylphenylsilylene) derivative as a photoinitiator of radical polymerization of hydrophilic vinyl monomers. Polymer Bulletin 29, 277–282 (1992). https://doi.org/10.1007/BF00944819

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  • DOI: https://doi.org/10.1007/BF00944819

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