Summary
Qualitative infrared and electronic spectroscopic data for a series of nickel(II) amine complexes suggest structures involving octahedral (transtetragonal) symmetry and associated with varying degrees of cation-anion interaction. N-methyl ligand substituents contribute significantly to ligand conformations, complex symmetry, and cation-anion steric interactions. From the electronic data, the parametersDq,B′,C,C/B′, β35, andZ* are determined for each complex and a spectrochemical and nephelauxetic series is proposed for the associated amine ligands.
Zusammenfassung
Die qualitative Auswertung von Daten aus Infrarot- und Elektronenspektroskopie von Nickel(II)-Amin-Komplexen erlaubte die Zuordnung einer oktaedrischen (trans-tetragonalen) Symmetrie mit verschieden abgestuften Kation-Anion-Wechselwirkungen. Substituenten am N-Methyl-Liganden tragen signifikant zur Ligandenkonformation, Komplexsymmetrie und Kation-Anion-Wechselwirkung bei. Aus den elektronenspektroskopischen Daten wurden die ParameterDq,B′,C,C/B′, β35 undZ* für jeden Komplex bestimmt und als Kriterium für eine Reihung der Aminliganden herangezogen.
Similar content being viewed by others
References
McLafferty R. W. (1973) Interpretation of Mass Spectra. Benjamin, New York, pp. 48–56
Tang S. C., Weinstein G. N., Holm R. H. (1972) J. Amer. Chem. Soc.95: 614
Curtis N. F. (1968) Coord. Chem. Rev.3: 3
Curtis N. F. (1963) J. Chem. Soc.: 4109
Barefield E. K., Bursh D. H. (1971) Inorg. Chem.10: 108
Hathaway B. J., Webster D. E. (1963) Proc. Chem. Soc. Lond.: 14
Brown D. S., Lee J. D., Melsom B. G. A., Hathaway B. J., Procter I. M., Tomlinson A. A. G. (1967) J. Chem. Soc. Chem. Commun.1967: 369
Rao C. N. R. (1963) Chemical Applications of Infrared Spectroscopy. Academic Press, New York, pp. 357–364
Martin L. Y., DeHayes L. J., Zompa L. J., Busch D. H. (1974) J. Amer. Chem. Soc.96: 4046
Urbach R. L. (1979) In: Melson G. A. (ed.) Coordination Chemistry of Macrocyclic Compounds. Plenum Press, New York, chapt. 5
Maki G. J. (1958) Chem. Phys.28: 651
Holtman M. S., Cummings S. C. (1976) Inorg. Chem.15: 660
Kolinski R. A., K-Daszkiewicz B. (1975) Inorg. Chim. Acta14: 237
Kobayashi H., K-Daszkiewicz B. (1972) Bull. Chem. Soc. Japan45: 2485
Buxtorf R., Kaden T. A. (1975) Helv. Chim. Acta57: 1035
Wagner F., Barefield E. K. (1976) Inorg. Chem.15: 408
Farago M. E., James J. M., Trew V. C. G. (1967) J. Chem. Soc. (A): 820
Pavkovic S. F., Meek D. W. (1965) Inorg. Chem.4: 1091
Durig J. F., Layton R., Sink D. W., Mitchell B. R. (1965) Spectrochim. Acta21: 1367
Lever A. B. P., Mantovani E. (1973) Can. J. Chem.51: 1567
Goodgame D. M. L., Venanzi L. M. (1963) J. Chem. Soc.: 616
Duff E. J. (1968) J. Chem. Soc. (A): 434
Nakamoto K. (1978) Infrared and Raman Spectra of Inorganic and Coordination Compounds, 3rd Edn. Wiley-Interscience, New York, p. 197
Adams D. M. (1967) Metal-Ligand and Related Vibrations. Arnold, London
Powell D. B., Sheppard N. (1961) Spectrochim. Acta17: 68
Jorgensen C. K. (1954) Acta Chem. Scand.8: 1495
Farago M. E., James J. M., Trew V. C. G. (1968) J. Chem. Soc. (A): 48
Cotton F. A., Wilkinson G. (1980) Advanced Inorganic Chemistry, A Comprehensive Text, 4th Edn. Wiley, New York
Swink L. N., Atoji M. (1960) Acta Cryst.13: 639
Huheey J. E. (1975) Inorganic Chemistry-Principles of Structure and Reactivity. S. I. Units Edn., pp. 310–369, 449
Jorgensen C. K. (1957) Acta Chem. Scand.11: 166
Karn J. L. (1966) Ph.D. Thesis. Ohio State University
Murrell J. N., Pople J. A. (1956) Proc. Phys. Soc. Lond.A 69: 245
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Roe, S.P., Hill, J.O. & Magee, R.J. An infrared and electronic spectroscopic study of a series of nickel(II) amine complexes. Monatsh Chem 122, 467–478 (1991). https://doi.org/10.1007/BF00809798
Received:
Revised:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF00809798