Skip to main content
SpringerLink
Log in

The potentiometric determination of stability constants of macrocyclic ethers using linear regression techniques

  • Original Papers
  • General Chemistry
  • Published:
Fresenius' Journal of Analytical Chemistry Aims and scope Submit manuscript

Summary

The stability constants of various stoichiometries of NaCl complexes of the macrocyclic ethers of 15-crown-5, benzo-15-crown-5, 18-crown-6 and benzo-18-crown-6 were measured by maintaining identical initial ion-ligand concentrations [A +0 ]=[Lo] and using the expression of the stability constant βi of a complex formation, 1/βi[Lo]n+m−1=(1−nP′)n(1−mP′)m/P′ where P′=PAL/[1+PAL(m−1)]. The potentiometric measurements were carried out in water with a glass membrane electrode in a computer-ion meter system.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Hwang JD, Winefordner JD (1988) Prog Analyt Spectrosc 11:209–249

    Google Scholar 

  2. Kolthoff IM, Chanttoni MK (1980) Anal Chem 52:1039–1044

    Google Scholar 

  3. Lehn JM (1988) Angew Chem Int Ed Engl 27:89–112

    Google Scholar 

  4. Cram DJ (1988) Angew Chem Int Ed Engl 27:1009–1112

    Google Scholar 

  5. Izatt RM, Pawlak K, Bradshaw JS, Breuning R (1991) Chem Rev 91:1721–2085

    Google Scholar 

  6. Michaux G, Reisse J (1982) J Am Chem Soc 104:6895–6899

    Google Scholar 

  7. Erk Ç (1983) Fresenius Z Anal Chem 316:477–481

    Google Scholar 

  8. Erk Ç (1990) J Phys Chem 94:8617–8620

    Google Scholar 

  9. Erk Ç (1991) J Mol Liqs 248:17–29

    Google Scholar 

  10. Erk Ç (1991) Thermochim Acta 180:317–324

    Google Scholar 

  11. Çakır U, Erk Ç (1991) Thermochim Acta 178:67–73

    Google Scholar 

  12. Göçmen A, Bulut M, Erk Ç (1993) Pure Appl Chem 65:447–450

    Google Scholar 

  13. Savaş G, Göçmen A, Erk Ç (1991) unpublished results

  14. Frensdorf HK (1971) J Am Chem Soc 93:600–606

    Google Scholar 

  15. Kauffmann E, Lehn JM, Sauvage JP (1976) Helv Chim Acta 59:1099–1111

    Google Scholar 

  16. Höiland H, Ringseth JA, Brun TS (1979) J Sol Chem 78:779–792

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Faculty of Science, Chemistry Department, Maslak, Istanbul Technical University, TR-80626, Istanbul, Turkey

    Ayten Göçmen & Çakıl Erk

Authors
  1. Ayten Göçmen
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Çakıl Erk
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Submitted to IUPAC, International Symposium on Macrocyclic Ligands for the Design of New Materials, 1992, Surrey, UK

Rights and permissions

Reprints and permissions

About this article

Cite this article

Göçmen, A., Erk, Ç. The potentiometric determination of stability constants of macrocyclic ethers using linear regression techniques. Fresenius J Anal Chem 347, 471–474 (1993). https://doi.org/10.1007/BF00324235

Download citation

  • Received:

  • Revised:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00324235

Keywords

Search

Navigation