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Organosilicon Fragrance Carriers

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Abstract

Five different organosilicon carriers, with various molecular architectures - [(poly-(dimethylsiloxane-co- methylsiloxane) (containing 61 % of [–SiMeHO-] monomeric units) (P), silicone resin (Q), tetramethyldisiloxane (M) tetramethylcyclotetrasiloxane (D) and tris (dimethylsilyl)methane [HC(SiMe2H)3, (T)] were covalently bonded with model fragrant systems, including 1- and 2-phenylethyl alcohol, acetophenone, 2-phenylpropionic aldehyde, geraniol, 2-phenyl-1-propyl alcohol, 2-octanone and octyl aldehyde in order to obtain novel controlled fragrance release systems. Hydrolytic release of the fragrances was studied under base (NaOH) and acid (HCl) catalysis. It has been shown that polymer carriers allow for a controlled slow release of the relevant fragrant ingredients from the conjugates, whereas the low molecular weight systems (M, D and T) more easily cleave off fragrant moieties.

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Authors and Affiliations

  1. Centre of Molecular and Macromolecular Studies, Polish Academy of Science, Sienkiewicza 112, 90-363, Lodz, Poland

    Tomasz Ganicz, J. Kurjata & Wlodzimierz A. Stanczyk

  2. GE Global Research, 1 Research Circle, Niskayuna, NY, 12309, USA

    Robert J. Perry

Authors
  1. Tomasz Ganicz
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  2. J. Kurjata
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  3. Robert J. Perry
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  4. Wlodzimierz A. Stanczyk
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Corresponding author

Correspondence to Wlodzimierz A. Stanczyk.

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Ganicz, T., Kurjata, J., Perry, R.J. et al. Organosilicon Fragrance Carriers. Silicon 7, 333–341 (2015). https://doi.org/10.1007/s12633-015-9309-4

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  • DOI: https://doi.org/10.1007/s12633-015-9309-4

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