Skip to main content
Log in

Cross-sectional TEM and KOH-Etch Studies of Extended Defects in 3C-SiC p + n Junction Diodes Grown on 4H-SiC Mesas

  • Published:
Journal of Electronic Materials Aims and scope Submit manuscript

Abstract

This article presents cross-sectional transmission electron microscopy and molten-potassium hydroxide etching studies of (111) 3C-SiC diodes which we previously reported to be free of forward-voltage drift despite abundant electroluminescent linear features presumed to be defects. Our results show that the majority of linear features are stacking faults lying in inclined {111} planes. Additionally, high densities of isolated etch pits (106–108 cm−2) are observed in 3C films grown on stepped 4H mesas, while 3C films nucleated on step-free 4H mesas exhibited orders of magnitude fewer etch pits and stacking faults. Defect formation mechanisms whose impetuses are steps on the 4H-SiC pregrowth mesa are discussed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. H. Lendenmann, F. Dahlquist, N. Johansson, R. Söderholm, P.Å. Nilsson, J.P. Bergman, P. Skytt, Mater. Sci. Forum 353–356, 727 (2001)

    Google Scholar 

  2. J.P. Bergman, H. Lendenmann, P.Å. Nilsson, U. Lindefelt, P. Skytt, Mater. Sci. Forum 353–356, 299 (2001)

    Google Scholar 

  3. M.S. Miao, S. Limpijumnong, W.R.L. Lambrecht, Appl. Phys. Lett. 79 (26), 4360 (2001)

    Article  CAS  Google Scholar 

  4. A. Agarwal, H. Fatima, S. Haney, and S.-H. Ryu, IEEE Electr. Device L. 28(7), 587 (2007)

    Google Scholar 

  5. M. Bhatnager, B.J. Baliga, IEEE Trans. Electron Dev. 40 (3), 645 (1993)

    Article  Google Scholar 

  6. P.G. Neudeck, D.J. Spry, A.J. Trunek, Mater. Sci. Forum 527–529, 1335 (2006)

    Google Scholar 

  7. K.M. Speer, D.J. Spry, A.J. Trunek, P.G. Neudeck, M.A. Crimp, J.T. Hile, C. Burda, P. Pirouz, Mater. Sci. Forum 556–557, 223 (2007)

    Google Scholar 

  8. K.M. Speer, P.G. Neudeck, M.A. Crimp, C. Burda, P. Pirouz, Phys. Stat. Sol. (a) 204 (7), 2216 (2007)

    Article  CAS  Google Scholar 

  9. P.G. Neudeck, J.A. Powell, A.J. Trunek, X.R. Huang, M. Dudley, Mater. Sci. Forum 389–393, 311 (2002)

    Google Scholar 

  10. R.E. Stahlbush, M. Fatemi, J.B. Fedison, S.D. Arthur, L.B. Rowland, S. Wang, J. Electron Mater. 31 (5), 370 (2002)

    Article  CAS  Google Scholar 

  11. P.G. Neudeck, J.A. Powell, D.J. Spry, A.J. Trunek, X. Huang, W.M. Vetter, M. Dudley, M. Skowronski, J. Liu, Mater. Sci. Forum 433–436, 213 (2003)

    Article  Google Scholar 

  12. P.G. Neudeck, H. Du, M. Skowronski, D.J. Spry, and A.J. Trunek, J. Phys. D: Appl. Phys. (2007, in press)

  13. A. Galeckas, J. Linnros, P. Pirouz, Appl. Phys. Lett. 81 (5), 883 (2002)

    Article  CAS  Google Scholar 

  14. U. Lindefelt, H. Iwata, S. Öberg, P.R. Briddon, Phys. Rev. B 67 (15) 155204 (2003)

    Article  CAS  Google Scholar 

  15. J.A. Powell, P.G. Neudeck, A.J. Trunek, P.B. Abel, Mater. Sci. Forum 483–485, 753 (2005)

    Google Scholar 

  16. J.A. Powell, D.J. Larkin, Phys. Stat. Sol. (b) 202, 529 (1997)

    Article  CAS  Google Scholar 

  17. C. Cheng, R.J. Needs, V. Heine, N. Churcher, Europhys. Lett. 3 (4), 475 (1987)

    Article  CAS  Google Scholar 

  18. V. Heine, C. Cheng, R.J. Needs, J. Am. Ceram. Soc. 74 (10), 2630 (1991)

    Article  CAS  Google Scholar 

  19. P. Pirouz, Solid State Phenom. 56, 107 (1997)

    CAS  Google Scholar 

  20. F.R. Chien, S.R. Nutt, W.S. Yoo, T. Kimoto, H. Matsunami, J. Mater. Res. 9 (4), 940 (1994)

    Article  CAS  Google Scholar 

  21. P.G. Neudeck and J.A. Powell, in Recent Major Advances in SiC, eds. W.J. Choyke, H. Matsunami, and G. Pensl (Heidelberg, Germany: Springer-Verlag, 2003), pp. 179–205

  22. P.G. Neudeck, A.J. Trunek, D.J. Spry, J.A. Powell, H. Du, M. Skowronski, X.R. Huang, M. Dudley, Chem Vap Deposition 12, 531 (2006)

    Article  CAS  Google Scholar 

Download references

Acknowledgements

The authors thank Mr. Henk Colijn (Ohio State University) for assistance with XTEM specimen lift-out. The help of Dr. Augustinas Galeckas (University of Oslo) also deserves sound recognition, and Dr. Robert Stahlbush’s (Naval Research Laboratory) contributions are humbly acknowledged as well. This work was funded by NASA GSRP fellowship Grant #04-HA03H.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Kevin M. Speer.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Speer, K.M., Neudeck, P.G., Spry, D.J. et al. Cross-sectional TEM and KOH-Etch Studies of Extended Defects in 3C-SiC p + n Junction Diodes Grown on 4H-SiC Mesas. J. Electron. Mater. 37, 672–680 (2008). https://doi.org/10.1007/s11664-007-0297-z

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11664-007-0297-z

Keywords

Navigation