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Mechanism of surface modification of the Ti-6Al-4V alloy using a gas tungsten arc heat source

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Abstract

The surface modification of a Ti-6Al-4V alloy using a gas tungsten arc, as a heat source, was studied. The experimental results show that the titanium alloy surface can be melted and nitrided using pure nitrogen or a nitrogen/argon mixture shielding atmosphere. The resolidified surfaces are 0.9 to 1.2-mm thick and contain titanium nitride dendrites, α-titanium, and α″-titanium (martensite). The average dendrite arm spacing is influenced by the electrode speed. Small titanium nitride dendrites are homogeneously distributed in the resolidified surfaces. The microstructure and phase constitution in the resolidified surfaces were determined and analyzed, and the mechanism of the formation of titanium nitrides is discussed. The results show that the nitriding kinetics obey parabolic laws and are, therefore, controlled by nitrogen diffusion. The nitrogen-concentration depth profiles, calculated using Fick’s second law of diffusion, are compared to experimental nitrogen depth profiles, showing satisfactory agreement.

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References

  1. R. Hanzell: Met. Progr., 1954, vol. 65, p. 89.

    Google Scholar 

  2. R.A. Rowntree: 2nd Eur. Space Mechanisms and Tribology Symp., Conf. Proc, J.L. Murray, Ed., Meersburg, 1985, pp. 167–71.

  3. E. Mitchell and P. Brotheron: J. Inst. Met., 1964–1965, vol. 93, p. 381.

    Google Scholar 

  4. H.J. Brading: Ph.D. Thesis, University of Birmingham, Birmingham, 1992.

    Google Scholar 

  5. M. Miyagi, Y. Sato, T. Mizuno, and S. Sawada: Titanium ’80, 4th Int. Conf. on Titanium, Conf. Proc., TMS-AIME, Warrendale, PA, 1980, vol. 4, p. 2867.

    Google Scholar 

  6. J.A. Davidson and A.K. Mishra: Surface Modification Technologies V, Conf. Proc., T.S. Sudarshan and J.F. Braza, eds., Institute of Materials, Birmingham, 1992, p. 1.

    Google Scholar 

  7. M. Salehi, T. Beil, and P.H. Morten: Surface Modification Technologies IV, Conf. Proc., TMS, Birmingham, 1991, pp. 991–1002.

    Google Scholar 

  8. S. Yeramaredddy and S. Bahadur: Wear, 1992, vol. 157, p. 245.

    Article  Google Scholar 

  9. O.V. Akgun and O.T. Inal: J. Mater. Sci., 1994, vol. 29, p. 1159.

    Article  CAS  Google Scholar 

  10. H. Xin, S. Mridha, and T.N. Baker: J. Mater. Sci., 1996, vol. 31, p. 22.

    Article  CAS  Google Scholar 

  11. P.H. Morten, T. Bell, A. Weisheit, J. Kroll, B. Mordike, and K. Sagoo: Surface Modification Technologies V, Conf. Proc., Institute of Materials, Birmingham, 1992, pp. 593–609.

    Google Scholar 

  12. W.M. Weerasinghe, D.R.F. West, and J. de Damborenea: J. Mater. Processing Technol., 1996, vol. 58, p. 79.

    Article  Google Scholar 

  13. B.L. Mordike: Laser Surface Treatment of Metals, Conf. Proc., C.W. Draper and P. Nazoldi, eds., Martinus Nijhoff, Dordrecht, 1986, pp. 451–60.

    Google Scholar 

  14. M. Labudovic and T.I. Khan: J. Mater. Sci. Technol., 1998, vol. 14, p. 357.

    CAS  Google Scholar 

  15. R.A. Andrievskii, J.F. Khromov, D.E. Svitsunov, and R.S. Jurkova: Russ. J. Phys. Chem., 1983, vol. 57, p. 996.

    Google Scholar 

  16. H.A. Wriedt and J.L. Murray: Phase Diagrams of Binary Titanium Alloys, Conf. Proc., J.L. Murray, ed., ASM INTERNATIONAL, Metals Park, OH, 1987, p. 176.

    Google Scholar 

  17. A.D. McQuillan and A.K. McQuillan: Titanium, Academic Press, New York, NY, 1956.

    Google Scholar 

  18. J. Debuigne: Metaux Corrosion Industrie, 1967, vol. 89, p. 499.

    Google Scholar 

  19. J.P. Bars, E. Etchessahar, and J. Debuigne: J. Less Common Met., 1977, vol. 52, p. 51.

    Article  CAS  Google Scholar 

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Labudovic, M., Kovacevic, R., Kmecko, I. et al. Mechanism of surface modification of the Ti-6Al-4V alloy using a gas tungsten arc heat source. Metall Mater Trans A 30, 1597–1603 (1999). https://doi.org/10.1007/s11661-999-0096-7

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