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Cyanido-bridged one-dimensional systems assembled from [ReIVCl4(CN)2]2− and [MII(cyclam)]2+ (M = Ni, Cu) precursors

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  • Special Topic · Molecular Magnetism
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Abstract

Three new cyanido-bridged heterometallic ReIVNiII and ReIVCuII one-dimensional systems were synthesized and extensively characterized both structurally and magnetically. Single-crystal X-ray diffraction analysis revealed that these compounds display a common topology, with chains composed of alternating [ReIVCl4(CN)2]2− and [MII(cyclam)]2+ (M = Ni in 1, Cu in 2) or [CuII(N,N′-dimethylcyclam)]2+ (in 3) building units. Two different chain orientations with a tilt angle of ca. 51° to 55° are present in the crystal packing of these compounds. The magnetic susceptibility measurements suggest the presence of intrachain ferromagnetic interactions between the S = 3/2 ReIV centers and the 3d metal ions: S = 1 NiII or S = 1/2 CuII. At low temperature, a three-dimensional ordered magnetic phase induced by interchain antiferromagnetic interactions (antiferromagnetic for 1 and 2; canted antiferromagnetic for 3) is detected for the three compounds.

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Authors and Affiliations

  1. CNRS, CRPP, UPR 8641, F-33600, Pessac, France

    Indrani Bhowmick, Pierre Dechambenoit, Elizabeth A. Hillard, Céline Pichon, Ie-Rang Jeon & Rodolphe Clérac

  2. Univ. Bordeaux, CRPP, UPR 8641, F-33600, Pessac, France

    Indrani Bhowmick, Pierre Dechambenoit, Elizabeth A. Hillard, Céline Pichon, Ie-Rang Jeon & Rodolphe Clérac

  3. Department of Chemistry, University of California, Berkeley, California, 94720, USA

    T. David Harris

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  1. Indrani Bhowmick
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  2. T. David Harris
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  7. Rodolphe Clérac
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Correspondence to Rodolphe Clérac.

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Bhowmick, I., Harris, T.D., Dechambenoit, P. et al. Cyanido-bridged one-dimensional systems assembled from [ReIVCl4(CN)2]2− and [MII(cyclam)]2+ (M = Ni, Cu) precursors. Sci. China Chem. 55, 1004–1011 (2012). https://doi.org/10.1007/s11426-012-4592-z

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  • DOI: https://doi.org/10.1007/s11426-012-4592-z

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