Abstract
For in situ groundwater remediation, polyelectrolyte-modified nanoscale zerovalent iron particles (NZVIs) have to be delivered into the subsurface, where they degrade pollutants such as trichloroethylene (TCE). The effect of groundwater organic and ionic solutes on TCE dechlorination using polyelectrolyte-modified NZVIs is unexplored, but is required for an effective remediation design. This study evaluates the TCE dechlorination rate and reaction by-products using poly(aspartate) (PAP)-modified and bare NZVIs in groundwater samples from actual TCE-contaminated sites in Florida, South Carolina, and Michigan. The effects of groundwater solutes on short- and intermediate-term dechlorination rates were evaluated. An adsorbed PAP layer on the NZVIs appeared to limit the adverse effect of groundwater solutes on the TCE dechlorination rate in the first TCE dechlorination cycle (short-term effect). Presumably, the pre-adsorption of PAP “trains” and the Donnan potential in the adsorbed PAP layer prevented groundwater solutes from further blocking NZVI reactive sites, which appeared to substantially decrease the TCE dechlorination rate of bare NZVIs. In the second and third TCE dechlorination cycles (intermediate-term effect), TCE dechlorination rates using PAP-modified NZVIs increased substantially (~100 and 200%, respectively, from the rate of the first spike). The desorption of PAP from the surface of NZVIs over time due to salt-induced desorption is hypothesized to restore NZVI reactivity with TCE. This study suggests that NZVI surface modification with small, charged macromolecules, such as PAP, helps to restore NZVI reactivity due to gradual PAP desorption in groundwater.
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Acknowledgments
The authors are thankful for financial support from (1) the Thailand Research Fund (TRF) (MRG5680129), (2) the National Nanotechnology Centre (Thailand), a member of the National Science and Technology Development Agency, through grant number P-11-00989, (3) the National Research Council of Thailand (grant no. R2556B070 and R2555C010), and (4) the U.S. EPA (R830898 and R833326), NSF (BES-068646 and EF-0830093), and Department of Defense through the Strategic Environmental Research and Development Program (W912HQ-06-C-0038).
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Simplified TCE reduction pathways, Fe0 content determination, Ohshima’s soft particle analysis and mass balance of the dechlorination studies. This material is available free of charge via the Internet. (DOC 317 kb)
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Phenrat, T., Schoenfelder, D., Kirschling, T.L. et al. Adsorbed poly(aspartate) coating limits the adverse effects of dissolved groundwater solutes on Fe0 nanoparticle reactivity with trichloroethylene. Environ Sci Pollut Res 25, 7157–7169 (2018). https://doi.org/10.1007/s11356-015-5092-4
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DOI: https://doi.org/10.1007/s11356-015-5092-4