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Cyanide-bridged one-dimensional bimetallic complexes based on a tridentate copper(II) building block: synthesis, crystal structures and magnetic properties

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Abstract

The reactions of [MIII(CN)6]3− (M = Cr or Co) with CuII complexes of a tridentate schiff base [Cu(aemp)Cl] or [Cu(aemp)Ac]2 (Haemp = 2-[(2-amino-ethylimino)-methyl]-phenol) give rise to 1D cyanide-bridged bimetallic coordination polymers [Cu4(aemp)4(H2O)2][Cr(CN)6]Cl (1) and [Cu3(aemp)3(H2O)][Co(CN)6]·2H2O·MeOH (2). In complex 1, the six cyanide ligands of the [Cr(CN)6]3− moiety are involved in bridging, while in complex 2 only five cyanide ligands act as bridges to give a neutral chain. Magnetic studies reveal that complex 1 exhibits intermetallic ferromagnetic coupling, with J = 8.2 cm−1.

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Acknowledgments

This work was supported by 973 program (2013CB933403) and the National Natural Science Foundation of China (Project Nos.: 91222104 and 21171103). CCDC 974401-974402 contains the supplementary crystallographic data for this paper. The data can be obtained free of charge from the Cambridge Crystallographic Data Center via www.ccdc.cam.ac.uk/data_request/cif.

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Authors and Affiliations

  1. Department of Chemistry, Tsinghua University, Beijing, 100084, People’s Republic of China

    Shu-Tao Li, Chong-Chao Zhao, Ai-Li Cui & Hui-Zhong Kou

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  1. Shu-Tao Li
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  2. Chong-Chao Zhao
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  4. Hui-Zhong Kou
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Correspondence to Hui-Zhong Kou.

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Li, ST., Zhao, CC., Cui, AL. et al. Cyanide-bridged one-dimensional bimetallic complexes based on a tridentate copper(II) building block: synthesis, crystal structures and magnetic properties. Transition Met Chem 39, 387–392 (2014). https://doi.org/10.1007/s11243-014-9812-2

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