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Crystal structures and physicochemical properties of mixed salts of ammonium nitrate and sulfate

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Abstract

Mixed salts (NH4)2SO4·2NH4NO3 (1) and (NH4)2SO4·3NH4NO3 (2) were synthesized and studied by X-ray diffraction analysis. The unit cell parameters of these salts were determined and their crystal structures were solved. The thermal stability of the salts was studied by differential scanning calorimetry and thermogravimetric analysis. The temperatures and enthalpies of incongruent melting of compounds 1 and 2 were determined. The enthalpies of formation from the constituent salts were estimated.

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Authors and Affiliations

  1. Department of Chemistry, M. V. Lomonosov Moscow State University, Build. 3, 1 Leninskie Gory, 119991, Moscow, Russian Federation

    T. S. Babkina, N. B. Golovina, A. G. Bogachev, A. V. Olenev, A. V. Shevelkov & I. A. Uspenskaya

Authors
  1. T. S. Babkina
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  2. N. B. Golovina
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  3. A. G. Bogachev
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  4. A. V. Olenev
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  5. A. V. Shevelkov
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  6. I. A. Uspenskaya
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Corresponding author

Correspondence to T. S. Babkina.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 33—38, January, 2012.

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Babkina, T.S., Golovina, N.B., Bogachev, A.G. et al. Crystal structures and physicochemical properties of mixed salts of ammonium nitrate and sulfate. Russ Chem Bull 61, 33–39 (2012). https://doi.org/10.1007/s11172-012-0005-x

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  • DOI: https://doi.org/10.1007/s11172-012-0005-x

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