Skip to main content
SpringerLink
Log in

Spectroscopic and electrochemical study of dinuclear and mononuclear copper complexes with the bidentate ligand of the 2,2′-diquinoline series

  • Full Articles
  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

The newly synthesized complex (2) of copper(I) chloride with di-n-hexyl 2,2′-biquinoline-4,4′-dicarboxylate (L) was spectroscopically and electrochemically characterized. The X-ray diffraction study showed that the crystals of complex 2 consist of the dinuclear moieties [L2Cu1 2(μ-Cl)2] containing Cu2(μ-Cl)2 clusters. Spectrophotometric studies and ESI-mass spec-trometric measurements showed that after the dissolution of complex 2 in acetonitrile (AN) and N-methyl-2-pyrrolidone (NMP), the solution contained not only the dinuclear complexes [L2Cu1 2(μ-Cl)2] but also [L2Cu1]Cl, [LCu1Cl(Sol)], and [Cu1Cl(Sol)] (Sol is the solvent). The electrochemical data also confirm the conclusion that bridged dinuclear chloride complex 2 dissociates both in NMP and AN to form the tetrahedral bis-biquinoline complex [L2Cu1]Cl. In solutions of complex 2 in alcohols and N,N-dimethylformamide (DMF), only [L2Cu1]Cl and [Cu1Cl(Sol)] are present. In EtOH, AN, and DMF, [Cu1Cl(Sol)] undergoes disproportionation to [Cu11Cl(Sol)] and Cu0.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Comprehensive Coordination Chemistry II: From Biology to Nanotechnology, Eds J. A. McCleverty, T. J. Meyer, Vol. 1, Elsevier, Amsterdam, 2005.

    Google Scholar 

  2. F. Durola, J.-P. Savage, Angew. Chem., Int. Ed., 2007, 46, 3537.

    Article  CAS  Google Scholar 

  3. V. Balzani, A. Credi, S. Silvi, M. Venturi, Chem. Soc. Rev., 2006, 35, 1135.

    Article  CAS  Google Scholar 

  4. S. Kawano, N. Fujita, S. Shinkai, J. Am. Chem. Soc., 2004, 126, 8592.

    Article  CAS  Google Scholar 

  5. J. V. Steed and J. L. Etwood, Supramolecular Chemistry, John Wiley and Sons, Ltd, Chichester-New York—Weinheim—Brisbane—Singapore—Toronto, 2000.

    Google Scholar 

  6. V. V. Skopenko, A. Yu. Tsivadze, L. I. Savranskii, A. D. Garnovskii, Koordinatsionnaya khimiya [Coordination Chemistry], Akademkniga, Moscow, 2007, 487 p. (in Russian).

    Google Scholar 

  7. T. Nabeshima, T. Inaba, N. Furukawa, Inorg. Chem., 1993, 32, 1407.

    Article  CAS  Google Scholar 

  8. S. M. Scott, K. C. Gordon, Inorg. Chem., 1996, 35, 2452.

    Article  CAS  Google Scholar 

  9. Y. Jahng, J. Hazelrigg, D. Kimball, E. Riesgo, F. Wu, R. P. Thummel, Inorg. Chem., 1997, 36, 5390.

    Article  CAS  Google Scholar 

  10. M. D. Stephenson, M. J. Hardie, Dalton Trans., 2006, 3407.

  11. L. Carlucci, G. Ciani, A. Gramaccioli, D. M. Proserpio, S. Rizzato, Cryst. Eng. Commun., 2000, 1.

  12. O. Gonzalez, A. M. Atria, E. Spodine, J. Manzur, M. T. Garland, Acta Crystallogr., Sect. C: Cryst. Struct. Commun., 1993, 49, 1589.

    Article  Google Scholar 

  13. E. Kovari, R. Kramer, Z. Naturforsch., B: Chem. Sci., 1994, 49, 1324.

    Google Scholar 

  14. A. Alvarez-Larena, J. L. Brianso-Penalva, J. F. Piniella, R. Moreno-Esparza, L. Ruiz-Ramirez, A. Tovar, Z. Kristal-logr., 1995, 210, 543.

    Article  CAS  Google Scholar 

  15. A. M. Atria, P. Cortes, L. Acevedo, R. Trujillo, J. Manzur, O. Pena, R. Baggio, J. Chil. Chem. Soc., 2004, 49, 341.

    Article  CAS  Google Scholar 

  16. E. Tynan, P. Jensen, A. C. Lees, B. Moubaraki, K. S. Murray, P. E. Kruger, Cryst. Eng. Commun., 2005, 90.

  17. G. E. Kostakis, E. Nordlander, M. Haukka, J. C. Plakatouras, Acta Crystallogr., Sect. E: Struct. Rep. Online, 2006, 62, m77.

    Article  Google Scholar 

  18. M. Ghosh, P. Biswas, U. Floerke, K. Nag, Inorg. Chem., 2008, 47, 281.

    Article  CAS  Google Scholar 

  19. F. M. Menger, J.-J. Lee, K. S. Hagen, J. Am. Chem. Soc. 1991, 113, 4017.

    Article  CAS  Google Scholar 

  20. A. M. Atria, R. F. Baggio, M. T. Garland, E. Spodine, Acta Crystallogr., Sect. C: Cryst. Struct. Commun., 1994, 50, 864.

    Article  Google Scholar 

  21. B. Viossat, J. F. Gaucher, A. Mazurier, M. Selkti, A. Tomas, Z. Kristallogr.-New Cryst. Struct., 1998, 213, 329.

    CAS  Google Scholar 

  22. Y.-Q. Zheng, J. Sun, J.-L. Lin, Z. Anorg. Allg. Chem., 2001, 627, 90.

    Article  CAS  Google Scholar 

  23. J.-H. Yu, Z.-L. Lu, J.-Q. Xu, H.-Y. Bie, J. Lu, X. Zhang, New J. Chem., 2004, 28, 940.

    Article  CAS  Google Scholar 

  24. L. Wang, R.-B. Huang, L.-S. Long, L.-S. Zheng, E.-B. Wang, Z.-X. Xie, J. Coord. Chem., 2005, 58, 1439.

    Article  CAS  Google Scholar 

  25. Y. Muranishi, Y. Wang, M. Odoko, N. Okabe, Acta Crystallogr., Sect. C: Cryst. Struct. Commun., 2005, 61, m307.

    Article  Google Scholar 

  26. R. M. Williams, L. De Cola, F. Hartl, J. Lagref, J.-M. Planeix, A. De Cian, M. W. Hosseini, Coord. Chem. Rev., 2002, 230, 253.

    Article  CAS  Google Scholar 

  27. S. Kitagawa, M. Munakata, N. Miyaji, Bull. Chem. Soc. Jpn, 1983, 56, 2258.

    Article  CAS  Google Scholar 

  28. M. Munakata, M. Maekawa, S. Kitagawa, S. Nishibayashi, Kinki Daigaku Rikogakubu Kenkyu Hokoku, 1989, 25, 81; Chem.Abstrs, 1990, 112, 138441.

    Google Scholar 

  29. R. J. Butcher, E. Sinn, Inorg. Chem., 1977, 16, 2334.

    Article  CAS  Google Scholar 

  30. E. Sinn, J. Chem. Soc., Dalton Trans., 1976, 162.

  31. B. F. Ali, K. Al-Sou ’od, N. Al-Ja ’ar, A. Nassar, M. H. Zaghal, Z. Judeh, R. Al-Far, M. Al-Refai, M. Ibrahim, K. Mansi, K. H. Al-Obaidi, J. Coord. Chem., 2006, 59, 229.

    Article  CAS  Google Scholar 

  32. A. L. Gershuns, A. A. Verezubova, Zh. A. Tolstykh, Izv. Vuzov, Ser. Khim. i Khimich. Tekh. [Proceedings of Institutes: Chemistry and Chemical Technology], 1961, No. 1, 25.

    Google Scholar 

  33. H. R. Al-Obaidi, K. C. Gordon, J. J. McGarvey, S. E. J. Bell, J. Grimshaw, J. Phys. Chem., 1993, 97, 10942.

    Article  CAS  Google Scholar 

  34. R. Bilewicz, M. Pietraszkiewicz, Polyhedron, 1990, 9, 2353.

    Article  CAS  Google Scholar 

  35. T. V. Magdesieva, A. V. Dolganov, A. V. Yakimanskii, M. Ya. Goikhman, I. V. Podeshvo, V. V. Kudryavtsev, Electrochemistry, 2007, 43, 1194 [Russ. J. Electrochem. (Engl. Transl.), 2007,43].

    Google Scholar 

  36. K. Stolarczyk, R. Bilewicz, L. Siegfried, T. Kaden, Inorg. Chem. Acta, 2003, 348, 129.

    Article  CAS  Google Scholar 

  37. T. V. Magdesieva, A. V. Dolganov, P. M. Poleshchuk, A. V. Yakimanskii, M. Ya. Goikhman, I. V. Podeshvo, V. V. Kudryavtsev, Izv. Akad. Nauk, Ser. Khim., 2007, 1331 [Russ. Chem. Bull., Int. Ed., 2007, 56, 1380].

    Google Scholar 

  38. S. D. Lesesne, H. R. Henze, J. Am. Chem. Soc., 1942, 64, 1897.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, M. V. Lomonosov Moscow State University, Build. 3, 1 Leninskie Gory, 119992, Moscow, Russian Federation

    S. Z. Vatsadze, A. V. Dolganov, A. L. Maksimov & T. V. Magdesieva

  2. Institute of Macromolecular Compounds, Russian Academy of Sciences, 31 Bolshoiprosp., 199004, St. Petersburg, Russian Federation

    A. V. Yakimanskii, M. Ya. Goikhman & I. V. Podeshvo

  3. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    K. A. Lyssenko

Authors
  1. S. Z. Vatsadze
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. V. Dolganov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. V. Yakimanskii
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. M. Ya. Goikhman
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. I. V. Podeshvo
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. K. A. Lyssenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. A. L. Maksimov
    View author publications

    You can also search for this author in PubMed Google Scholar

  8. T. V. Magdesieva
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to T. V. Magdesieva.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 710–718, April, 2010

Rights and permissions

Reprints and permissions

About this article

Cite this article

Vatsadze, S.Z., Dolganov, A.V., Yakimanskii, A.V. et al. Spectroscopic and electrochemical study of dinuclear and mononuclear copper complexes with the bidentate ligand of the 2,2′-diquinoline series. Russ Chem Bull 59, 724–732 (2010). https://doi.org/10.1007/s11172-010-0153-9

Download citation

  • Received:

  • Revised:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11172-010-0153-9

Key words

Search

Navigation