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Synthesis and crystal structure of new double mercury silver phosphide iodide Hg12Ag41P88I41

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Abstract

New double mercury silver phosphide iodide Hg12Ag41P88I41 (1) was synthesized and its crystal structure was established. Compound 1 crystallizes in the cubic system. The characteristic feature of the crystal structure 1 is the presence of the anionic cage clusters P11 3−, which have been previously found in alkali metal compounds only. The well-ordered P11 3− clusters form a system of polyhedra, which encapsulate various disordered α-AgI-type fragments.

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Correspondence to A. V. Shevelkov.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 1882–1886, October, 2007.

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Oleneva, O.S., Shestimerova, T.A., Olenev, A.V. et al. Synthesis and crystal structure of new double mercury silver phosphide iodide Hg12Ag41P88I41 . Russ Chem Bull 56, 1948–1952 (2007). https://doi.org/10.1007/s11172-007-0302-y

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  • DOI: https://doi.org/10.1007/s11172-007-0302-y

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