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Synthesis, crystal structures, and electrochemistry of CuII complexes with tetradentate N2O2 ligands derived from 3,7-diazabicyclo[3.3.1]nonan-9-one

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Abstract

New copper(II) complexes with tetradentate ligands derived from 1,5-diphenyl-3,7-diazabicyclo[3.3.1]nonan-9-one and containing the N,N′-2-hydroxyethyl, 2-methoxyethyl, and carboxymethyl substituents were synthesized. The crystal structures of the complexes were established and the complexes were studied by cyclic voltammetry. The ligands are preorganized for complexation and are highly complementary for a divalent copper cation.

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Authors and Affiliations

  1. Department of Chemistry, M. V. Lomonosov Moscow State University, 1 Leninskie Gory, 119992, Moscow, Russian Federation

    S. Z. Vatsadze, V. S. Tyurin, N. V. Zyk, R. D. Rakhimov & K. P. Butin

  2. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation

    A. V. Churakov & L. G. Kuz'mina

  3. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    E. V. Avtomonov

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  1. S. Z. Vatsadze
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  2. V. S. Tyurin
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  3. N. V. Zyk
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  4. A. V. Churakov
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  5. L. G. Kuz'mina
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  6. E. V. Avtomonov
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  7. R. D. Rakhimov
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  8. K. P. Butin
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1773–1782, August, 2005.

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Vatsadze, S.Z., Tyurin, V.S., Zyk, N.V. et al. Synthesis, crystal structures, and electrochemistry of CuII complexes with tetradentate N2O2 ligands derived from 3,7-diazabicyclo[3.3.1]nonan-9-one. Russ Chem Bull 54, 1825–1835 (2005). https://doi.org/10.1007/s11172-006-0044-2

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  • DOI: https://doi.org/10.1007/s11172-006-0044-2

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