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Facile one-step synthesis of N-doped carbon nanotubes/N-doped carbon nanofibers hierarchical composites by chemical vapor deposition

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Abstract

The composites consisting of nitrogen-doped carbon nanotubes (N-CNTs) and nitrogen-doped carbon nanofibers (N-CNFs) were fabricated using a mixture of nickel foam (template) and imidazole (solid precursor) in a facile one-step chemical vapor deposition (CVD) process. The morphology and microstructure of the N-doped carbon nanotubes/N-doped carbon nanofibers hierarchical composites (N-CNTs/N-CNFs) were determined by scanning electron microscopy, transmission electron microscopy, X-ray diffraction, Raman spectra, and X-ray photoelectron spectroscopy. The results indicated that the sample manifests regular hierarchical composites, great graphitization, and nitrogen doping. Furthermore, a probable growth mechanism is presented to analyze the composites.

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References

  • Aksak M, Selamet Y (2010) Carbon nanotube diameter tuning using hydrogen amount and temperature on SiO2/Si substrates. Appl Phys A Mater Sci Process 100:213–222

    Article  CAS  Google Scholar 

  • Cai J, Wu C, Yang SR, Zhu Y, Shen PK, Zhang K (2017) Templated and catalytic fabrication of N-doped hierarchical porous carbon–carbon nanotube hybrids as host for lithium–sulfur batteries. ACS Appl Mater Interfaces 9:33876–33886

    Article  CAS  Google Scholar 

  • Ding YL, Kopold P, Hahn K, van Aken PA, Maier J, Yu Y (2016) Facile solid-state growth of 3D well-interconnected nitrogen-rich carbon nanotube-graphene hybrid architectures for lithium–sulfur batteries. Adv Funct Mater 26:1112–1119

    Article  CAS  Google Scholar 

  • Dong Q, Wang G, Hu H, Yang G, Qing BQ, Ling Z, Qiu JS (2013) Ultrasound-assisted preparation of electrospun carbon nanofiber/graphene composite electrode for supercapacitors. J Power Sources 243:350–353

    Article  CAS  Google Scholar 

  • Fan ZJ, Yan J, Zhi LJ, Zhang Q, Wei T, Feng J, Zhang ML, Qian WZ, Wei F (2010) A three-dimensional carbon nanotube/graphene sandwich and its application as electrode in supercapacitors. Adv Mater 22:3723–3728

    Article  CAS  Google Scholar 

  • Ghosh K, Kumar M, Maruyama T, Ando Y (2010) Controllable growth of highly N-doped carbon nanotubes from imidazole: a structural, spectroscopic and field emission study. J Mater Chem 20:4128

    Article  CAS  Google Scholar 

  • Guo QH, Zhou XP, Li XY, Chen SL, Seema A, Greiner A, Hou HQ (2009) Supercapacitors based on hybrid carbon nanofibers containing multiwalled carbon nanotubes. J Mater Chem 19:2810–2816

    Article  CAS  Google Scholar 

  • Guo QH, Zhao D, Liu SW, Chen SL, Hanif M, Hou HQ (2014) Free-standing nitrogen-doped carbon nanotubes at electrospun carbon nanofibers composite as an efficient electrocatalyst for oxygen reduction. Electrochim Acta 138:318–324

    Article  CAS  Google Scholar 

  • Hou HQ, Reneker DH (2004) Carbon nanotubes on carbon nanofibers: a novel structure based on electrospun polymer nanofibers. Adv Mater 16:69–73

    Article  CAS  Google Scholar 

  • Huczko A (2002) Synthesis of aligned carbon nanotubes. Appl Phys A Mater Sci Process 74:617–638

    Article  CAS  Google Scholar 

  • Jung M, Yong Eun K, Lee JK, Baik YJ, Lee KR, Wan Park J (2011) Growth of carbon nanotubes by chemical vapor deposition. Diam Relat Mater 10:1235–1240

    Article  Google Scholar 

  • Kim YS, Kumar K, Fisher FT, Yang EH (2012) Out-of-plane growth of CNTs on graphene for supercapacitor applications. Nanotechnology 23:15301–15307

    Article  Google Scholar 

  • Kim H, Huang XK, Guo X, Wen ZH, Cui SM, Chen JH (2014) Novel hybrid carbon nanofiber/highly branched graphene nanosheet for anode materials in lithium-ion batteries. ACS Appl Mater Interfaces 6:18590–18596

    Article  CAS  Google Scholar 

  • Landi BJ, Ganter MJ, Cress CD, Dileo RA, Raffaelle RP (2009) Carbon nanotubes for lithium ion batteries. Energy Environ Sci 2:638–654

    Article  CAS  Google Scholar 

  • Li HF, Wu F, Wang C, Zhang PX, Hu HY, Xie N, Pan M, Zeng ZL, Deng SG, Wu KV, Dai GP (2018) One-step chemical vapor deposition synthesis of 3D N-doped carbon nanotube/N-doped graphene hybrid material on nickel foam. Nanomaterials 8:700

    Article  Google Scholar 

  • Liu J, Zhang Y, Ionescu MI, Li R, Sun X (2011) Nitrogen-doped carbon nanotubes with tunable structure and high yield produced by ultrasonic spray pyrolysis. Appl Surf Sci 257:7837–7844

    Article  CAS  Google Scholar 

  • Liu D, Zhang XP, Sun ZC, You TY (2013) Free-standing nitrogen-doped carbon nanofiber films as highly efficient electrocatalysts for oxygen reduction. Nanoscale 5:9528

    Article  CAS  Google Scholar 

  • Minier, Behrens, JR RB, Bulusu A (1995) Solid-phase thermal decomposition of 2,4-dinitroimidazole (2,4-DIN). Mrs Proceedings 418:111–117

  • Paraknowitsch JP, Thomas A (2013) Doping carbons beyond nitrogen: an overview of advanced heteroatom doped carbons with boron, sulphur and phosphorus for energy applications. Energy Environ Sci 6:2839

    Article  CAS  Google Scholar 

  • Park M, Jung Y, Kim J, Lee HI, Cho J (2013) Synergistic effect of carbon nanofiber/nanotube composite catalyst on carbon felt electrode for high-performance all-vanadium redox flow battery. Nano Lette 13:4833–4839

    Article  CAS  Google Scholar 

  • Peter KT, Vargo JD, Rupasinghe TP, Jesus DA, Tivanski AV, Sander EA, Myung NV, Cwiertny DM (2016) Synthesis, optimization, and performance demonstration of electrospun carbon nanofiber–carbon nanotube composite sorbents for point-of-use water treatment. ACS Appl Mater Interfaces 8:11431–11440

    Article  CAS  Google Scholar 

  • Sharifi T, Nitze F, Barzegar HR, Tai CW, Mazurkiewicz M, Malolepszy A, Stobinski L, Wågberg T (2012) Nitrogen doped multi walled carbon nanotubes produced by CVD-correlating XPS and Raman spectroscopy for the study of nitrogen inclusion. Carbon 50:3535–3541

    Article  CAS  Google Scholar 

  • Sheng ZH, Shao L, Chen JJ, Bao WJ, Wang FB, Xia XH (2011) Catalyst-free synthesis of nitrogen-doped graphene via thermal annealing graphite oxide with melamine and its excellent electrocatalysis. ACS Nano 6:4350–4358

    Article  Google Scholar 

  • Song JX, Yu ZX, Gordin ML, Wang DH (2016) Advanced sulfur cathode enabled by highly crumpled nitrogen-doped graphene sheets for high-energy-density lithium–sulfur batteries. Nano Lette 16:864–870

    Article  CAS  Google Scholar 

  • Su DW, Cortie M, Wang GX (2017) Fabrication of N-doped graphene-carbon nanotube hybrids from prussian blue for lithium-sulfur batteries. Adv Energy Mater 7:1602014

    Article  Google Scholar 

  • Tian GL, Zhao MQ, Yu D, Kong XY, Huang JQ, Zhang Q, Wei F (2014) Nitrogen-doped graphene/carbon nanotube hybrids: in-situ formation on bifunctional catalysts and their superior electrocatalytic activity for oxygen evolution/reduction reaction. Small 11:2251–2259

    Article  Google Scholar 

  • Wang T, Song DF, Zhao H, Chen JY, Zhao CH, Chen LL, Chen WJ, Zhou JY, Xie E (2015) Facilitated transport channels in carbon nanotube/carbon nanofiber hierarchical composites decorated with manganese dioxide for flexible supercapacitors. J Power Sources 274:709–717

    Article  CAS  Google Scholar 

  • Yan Z, Ma LL, Zhu Y, Lahiri I, Hahm MG, Liu Z, Yang SB, Xiang CS, Lu W, Peng Z, Sun ZZ, Kittrell C, Lou J, Choi WB, Ajayan PM, Tour JM (2013) Three-dimensional metal-graphene-nanotube multifunctional hybrid materials. ACS Nano 7:58–64

    Article  CAS  Google Scholar 

  • Yan XL, Li HF, Wang C, Jing BB, Hu HY, Xie N, Wu MH, Vinodgopal K, Dai GP (2018) Melamine as a single source for fabrication of mesoscopic 3D composites of N-doped carbon nanotubes on graphene. RSC Adv 8:12157–12164

    Article  CAS  Google Scholar 

  • Yang J, Wang SY, Ma ZP, Du ZL, Li CY, Song JJ, Wang GL, Shao GJ (2015) Novel nitrogen-doped hierarchically porous coralloid carbon materials as host matrixes for lithium–sulfur batteries. Electrochim Acta 159:8–15

    Article  CAS  Google Scholar 

  • Zeng LC, Zeng WC, Jiang Y, Wei X, Li WH, Yang CG, Yu YA (2014) Flexible porous carbon nanofibers-selenium cathode with superior electrochemical performance for both Li-se and Na-se batteries. Adv Energy Mater 5:1401377

    Article  Google Scholar 

  • Zhang SM, Zhang HY, Liu Q, Chen S (2013) Fe-N doped carbon nanotube/graphene composite: facile synthesis and superior electrocatalytic activity. J Mater Chem A 1:3302

    Article  CAS  Google Scholar 

  • Zhang LJ, Jiang YZ, Wang LW, Zhang C, Liu SX (2016) Hierarchical porous carbon nanofibers as binder-free electrode for high-performance supercapacitor. Electrochim Acta 196:189–196

    Article  CAS  Google Scholar 

  • Zhang YZ, Zhang Z, Liu S, Li GR, Gao XP (2018) Free-standing porous carbon nanofiber/carbon nanotube film as sulfur immobilizer with high areal capacity for lithium–sulfur battery. ACS Appl Mater Interfaces 10:8749–8757

    Article  CAS  Google Scholar 

  • Zhao L, Qiu YJ, Yu J, Deng XY, Dai CL, Bai XD (2013) Carbon nanofibers with radially grown graphene sheets derived from electrospinning for aqueous supercapacitors with high working voltage and energy density. Nanoscale 5:4902

    Article  CAS  Google Scholar 

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Acknowledgments

The assistance of Dr. Zhi-Qun Tian (HRTEM measurements) at Guangxi University is greatly appreciated.

Funding

The National Natural Science Foundation of China (Grants 51762032 and 51462022) and the Natural Science Foundation Major Project of Jiangxi Province of China (Grant 20152ACB20012) provided financial support for this research.

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Authors and Affiliations

  1. School of Materials Science and Engineering, Nanchang University, Nanchang, 330031, Jiangxi, China

    Hua-Fei Li, Long-Fei Liu & Ning Xie

  2. Department of Chemical Engineering, School of Environmental and Chemical Engineering, Nanchang University, Nanchang, 330031, Jiangxi, China

    Chen Wang, Ming Pan, Ping Wu, Xiao-Di Wang, Zheling Zeng & Gui-Ping Dai

  3. School for Engineering of Matter, Transport and Energy, Arizona State University, Tempe, AZ, 85287, USA

    Shuguang Deng

Authors
  1. Hua-Fei Li
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  2. Chen Wang
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  3. Long-Fei Liu
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  4. Ning Xie
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  5. Ming Pan
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  6. Ping Wu
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  7. Xiao-Di Wang
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  8. Zheling Zeng
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  9. Shuguang Deng
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  10. Gui-Ping Dai
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Correspondence to Shuguang Deng or Gui-Ping Dai.

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Li, HF., Wang, C., Liu, LF. et al. Facile one-step synthesis of N-doped carbon nanotubes/N-doped carbon nanofibers hierarchical composites by chemical vapor deposition. J Nanopart Res 22, 10 (2020). https://doi.org/10.1007/s11051-019-4726-8

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