Abstract
Various effects on the synthesis of titanium silicalite-1 (TS-1) were discussed in the non-TPAOH (tetrapropyl ammonium hydroxide) inorganic reactant synthesis system, in which cheap colloidal silica and TiCl3 aqueous solution, TiCl4 were used as the silicon and titanium sources, respectively, TPABr (tetrapropyl ammonium bromide) as the template reagent, and weak organic bases as the base source to provide the alkalinity needed for crystallization. The influence of diverse synthesis parameters such as different base sources, SiO2/TiO2 ratio, silicon source, titanium source, amounts of template, N2 protection, seed crystals, aging period, amount of water, crystallization temperature, and crystallization time have been investigated in detail.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
M. Taramasso, G. Perego, and B. Notari, US 4 410 501 (1983).
M. Padovan and P. Roffia, EP 299 430 (1989).
A. Thangaraj and S. Sivasanker, J. Chem. Soc., Chem. Commun 123 (1992).
A. Thangaraj, M.J. Eapan, and S. Sivasanker, Zeolites 12, 943 (1992).
M.A. Uguina, G. Ovejero, and R. Van Grieken, J. Chem. Soc., Chem. Commun. 27 (1994).
U. Muller and W. Steck, Stud. Surf. Sci. Catal. 84, 203 (1994).
Huanxin Gao, Jishuan Suo, and Shuben Li, J. Chem. Soc., Chem.Commun. 835, (1995).
A. Tuel, Zeolites. 16, 108 (1996).
S. Gontier and A. Tuel, Zeolites. 16, 184 (1996).
E. Jorda and A. Tuel, Zeolites. 19, 238 (1997).
Gang Li, Xinwen Guo, Xiangsheng Wang, et al., Appl.Catal. A. 185, 11 (1999).
Jicheng Zhou, and Xiangsheng Wang, Chin. J. Chem. 18, 42 (2000).
D. Trong On and L. Bonneviot, J. Mol. Catal. 74, 233 (1992).
F. Geobaldo, S. Bordiga, A. Zecchina, et al., Catal. Lett. 16, 109 (1992).
Huanxin Gao, Wenkui Lu, and Qingling Chen, Micro. Meso. Mater. 34, 307 (2000).
D.R.C. Huybrechts, L. De Bruycker, and P.A. Jaccobs. Nature 345, 240 (1990).
T. Tatsumi, M. Nakamura, S .Negishi, et. al., J. Chem. Soc., Chem. Commun. 61, 476 (1990).
M.G. Clerici and P. Ingallina, J. Catal. 140, 71 (1993).
Huanxin Gao, Gongxuan Lu, Jishuan Suo, and Shuben Li, Appl. Catal. 138, 27 (1996).
F. Maspero and U. Romano, J. Catal. 146, 476 (1994).
A. Thangaraj, R. Kumar, and P. Ratnasamy, Appl. Catal. 57, L1 (1990).
A. Thangaraj, S. Sivasanker, and P. Ratnasamy, J. Catal. 131, 294 (1991).
A. Thangaraj, S. Sivasanker, and P. Ratnasamy, J. Catal. 131, 690 (1991).
M. Sasidharan, Peng Wu, and Takashi Tatsumi, J. Catal. 205, 32 (2002).
C.V. Rode, U.N. Nehete, and M.K. Dongare, Catal. Commun. 4, 365 (2003).
R. Millini, E. Previde Massara, G. Perego, and G. Bellussi, J. Catal. 137, 497 (1992).
D.R.C. Huybrechts, P.L. Buskens, and P.A. Jaccobs., J. Mol. Catal. 71, 129 (1992).
B. Notari, Catal. Today. 18, 163 (1993).
B. Notari, Advances in Catalysis. 41, 253 (1996).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Ding, Y., Gao, Q., Wang, B. et al. Some New Features on Synthesis of Titanium Silicalite-1 in a Non-TPAOH Inorganic Reactant Synthetic System. J Porous Mater 12, 131–141 (2005). https://doi.org/10.1007/s10934-005-6770-2
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1007/s10934-005-6770-2