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Sodium Trihydrogen-1,4-Benzenediphosphonate: An Extended Coordination Network

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Abstract

Crystals of sodium trihydrogen-1,4-benzenediphosphonate, Na[H3bdp], were prepared from the addition of aqueous sodium hydroxide to an acidified solution of 1,4-benzenediphosphonic acid (H4bdp). These were shown by X-ray crystallography to crystallize in the space group P \( \bar{1} \), with cell parameters a = 5.7500(3) Å, b = 7.9180(5) Å, c = 10.4420(6) Å, α = 80.398(3)°, β = 76.844(4)° and γ = 81.389(4)°. The crystal structure revealed that the title compound forms a coordination network in which sodium-phosphonate sheets are pillared by the benzene rings into a three-dimensional structure.

Graphical abstract

Sodium trihydrogen-1,4-benzenediphosphonate, Na[H3bdp], forms a coordination network in which sodium-phosphonate sheets are pillared by the benzene rings into a three-dimensional structure.

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Acknowledgment

The Commonwealth Scholarship Commission is thanked for the award of a Commonwealth Fellowship to AAA.

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Authors and Affiliations

  1. Department of Chemistry, University of Bath, Claverton Down, Bath, BA2 7AY, UK

    Ayi A. Ayi, Andrew D. Burrows, Mary F. Mahon & Viorica M. Pop

  2. Department of Pure and Applied Chemistry, University of Calabar, P.M.B. 1115, Calabar, Nigeria

    Ayi A. Ayi

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  1. Ayi A. Ayi
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  2. Andrew D. Burrows
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  3. Mary F. Mahon
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  4. Viorica M. Pop
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Correspondence to Andrew D. Burrows.

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Ayi, A.A., Burrows, A.D., Mahon, M.F. et al. Sodium Trihydrogen-1,4-Benzenediphosphonate: An Extended Coordination Network. J Chem Crystallogr 41, 1165–1168 (2011). https://doi.org/10.1007/s10870-011-0064-0

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  • DOI: https://doi.org/10.1007/s10870-011-0064-0

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