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Phenyl 4-nitrobenzenesulfonate: Supramolecular Aggregation via \( {\text{R}}_{4}^{4} \)(28) and \( {\text{R}}_{4}^{4} \)(36) C–H···O Cages

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Abstract

In the crystal structure of the title compound, C12H9NO5S, the dihedral angle between the mean planes of the two aromatic rings is 52.96 (5)°. The supramolecular architecture is dictated by the alternation of \( {\text{R}}_{4}^{4} \)(28) and \( {\text{R}}_{4}^{4} \)(36) C–H···O cages. Two inversion related phenyl rings form slightly offset face to face π···π interactions.

Index Abstract

The supramolecular architecture of the title compound, Phenyl 4-nitrobenzenesulfonate is dictated by the alternation of \( {\text{R}}_{4}^{4} \)(28) and \( {\text{R}}_{4}^{4} \)(36) C–H···O cages. Two inversion related phenyl rings form slightly offset face to face π···π interactions

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Acknowledgment

NV thanks the University Grants Commission (UGC), Government of India for a minor research project grant [MRP-2219/06(UGC-SERO)].

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Authors and Affiliations

  1. Department of Chemistry, Urumu Dhanalakshmi College, Tiruchirappalli, 620 019, India

    Nagarajan Vembu

  2. Department of Chemistry, Louisiana State University, Baton Rouge, LA, 70803-1804, USA

    Frank R. Fronczek

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  1. Nagarajan Vembu
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Correspondence to Nagarajan Vembu.

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Vembu, N., Fronczek, F.R. Phenyl 4-nitrobenzenesulfonate: Supramolecular Aggregation via \( {\text{R}}_{4}^{4} \)(28) and \( {\text{R}}_{4}^{4} \)(36) C–H···O Cages. J Chem Crystallogr 39, 515–518 (2009). https://doi.org/10.1007/s10870-009-9523-2

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