Skip to main content

Advertisement

SpringerLink
Log in

Effect of povidone–iodine addition on the corrosion behavior of cp–Ti in normal saline

  • Published:
Journal of Materials Science: Materials in Medicine Aims and scope Submit manuscript

Abstract

The effect of various concentrations of povidone–iodine (PI) on the corrosion behavior of a commercially pure titanium alloy (Ti-1) has been investigated in normal saline solution to simulate the povidone–iodine addition in an oral environment. The open circuit potential, electrochemical impedance spectroscopy and potentiodynamic polarization measurements have been used to characterize the electrochemical phenomena occurring on the alloy surface. The open circuit potential values for Ti-1 in various concentrations of PI shift considerably towards noble direction as compared to pure normal saline. In the potentiodynamic polarization curve for Ti-1 in various solutions, the cathodic current density has increased for all concentrations of PI and the anodic current density has decreased. Only the 0.1% PI concentration is able to inhibit corrosion of Ti-1 in normal saline and the other higher concentrations studied, accelerate corrosion. The EIS data for Ti-1 in normal saline and in various concentrations of PI follows a one time constant circuit, suggesting the formation of a single passive film on Ti-1 which is not altered by the addition of PI to normal saline.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7

Similar content being viewed by others

References

  1. Demir A, Malkoc S, Sengun A, Koyuturk AE, Sener Y. Effects of chlorohexidine and povidone-iodine mouth rinses on the bond strength of an orthodontic composite. Angle Orthod. 2005;75(3):392–6.

    PubMed  Google Scholar 

  2. Barabas ES. Vinylamines. Encyclopedia of polymer science and engineering, vol. 17, 2nd ed. New York: Wiley; 1989. p. 219.

  3. Brittain HG. Analytical profiles of drug substances and excipients, vol. 25. New York: Academic Press; 1998. p. 433.

  4. Fuoss RM, Strauss VP. Viscosity of mixtures of polyelectrolytes and simple electrolytes. Ann NY Acad Sci. 1949;51:836.

    Article  CAS  ADS  Google Scholar 

  5. LaRocca R, LaRocca M-AK, Ansell JM. Microbiology of povidone-iodine. In: Digenis GA, Ansell J, editors. Proceedings of the international symposium on povidone. Kentucky: University of Kentucky College of Pharmacy; 1983. p. 101.

  6. Broussoulaux C. A New Antiseptic: polyvinylpyrrolidone-iodine. Dissertation, Doctorate of Medicine, University of Paris (France), 1965 (submitted).

  7. Cournoyer RF, Siggia S. Interaction of poly(vinyl-pyrrolidone) and iodine. J Polym Sci. 1974;12:603–12.

    CAS  Google Scholar 

  8. Daniels WE, Chiddix ME, Glickman SA. Lactam complexes of Br-HBr. J Org Chem. 1963;28:573.

    Article  CAS  Google Scholar 

  9. Ferguson AW, Scott JA, McGavigan J, Elton RA, McLean J, Schmidt U, et al. Comparison of 5% povidone-iodine solution against 1% povidone-iodine solution in preoperative cataract surgery antisepsis: a prospective randomized double blind study. Br J Ophthalmol. 2003;87:163–7.

    Article  CAS  PubMed  Google Scholar 

  10. Rahn R. Review presentation on PI antisepsis in oral cavity. Postgrad Med J. 1993;69(3):S84–92.

    Google Scholar 

  11. Valderrama LS. Clinical application of povidone iodine oral antiseptic 1% (Betadine mouthwash) & povidone iodine skin antiseptic 10% for the management of odontogenic and deep fascial space infections. Dermatology. 2006;212(1):112–4.

    Article  CAS  PubMed  MathSciNet  Google Scholar 

  12. Balaji SM. Sterilization and infection control. Text book of oral and maxillofacial surgery. Amsterdam: Elsevier; 2007. p. 80–96.

    Google Scholar 

  13. Balaji SM. Spread of odontogenic infections. Text book of oral and maxillofacial surgery. Amsterdam: Elsevier; 2007. p. 116–47.

    Google Scholar 

  14. Balaji SM. Therapeutics in oral surgery. Text book of oral and maxillofacial surgery. Amsterdam: Elsevier; 2007. p. 147–63.

    Google Scholar 

  15. ASTM Standard F2129-06, ASTM International, USA.

  16. Bhola R, Bhola SM, Mishra B, Olson DL. Electrochemical behavior of titanium and its alloys as dental implants in normal saline. Res Lett Phys Chem 2009;2009:Article ID 574359.

  17. Hsu CH, Mansfeld F. Technical note: concerning the conversion of the constant phase element parameter (Y0) into a capacitance. Corrosion. 2001;57:747–8.

    Article  CAS  Google Scholar 

  18. Chongdar S, Gunasekaran G, Kumar P. Corrosion inhibition of mild steel by aerobic biofilm. Electrochim Acta. 2005;50:4655–65.

    Article  CAS  Google Scholar 

  19. Cano E, Bastidas DM, Argyropoulos V, Fajardo S, Siaton A, Bastidas JM, Degrigny C. Electrochemical characterization of organic coatings for protection of historic steel artefacts. J Solid State Electrochem. 2009. doi:10.1007/S10008-009-0907-1.

  20. Pan J, Thierry D, Leygraf C. Electrochemical impedance spectroscopy study of the passive oxide film on titanium for implant application. Electrochim Acta. 1996;41(7–8):1143–53.

    Article  CAS  Google Scholar 

  21. Lavos-Valereto IC, Wolynec S, Ramires I, Guastaldi AC, Costa I. Electrochemical impedance spectroscopy characterization of passive film formed on implant Ti-6Al-7Nb alloy in Hank’s solution. J Mater Sci Mater Med. 2004;15(1):55–9.

    Article  CAS  PubMed  Google Scholar 

  22. Oliveira NTC, Guastaldi AC. Electrochemical stability and corrosion resistance of Ti–Mo alloys for biomedical applications. Acta Biomater. 2009;5(1):399–405.

    Article  CAS  PubMed  Google Scholar 

  23. Huynh N, Bottle SE, Notoya T, Trueman T, Hinton B, Schweinsberg DP. Carboxybenzotriazole as inhibitors for copper corrosion. Corros Sci. 2002;44:1257–76.

    Article  CAS  Google Scholar 

  24. Bhandari H, Sathiyanaranayan S, Choudhary V, Dhawan SK. Synthesis and characterization of processable polyaniline derivatives for corrosion inhibition. J Appl Polym Sci. 2009;111:2328–39.

    Article  CAS  Google Scholar 

  25. Umoren SA, Eduok UM, Oguzie EE. Corrosion inhibition of mild steel in 1 M H2SO4 by polyvinyl pyrrolidone and synergistic iodide additives. Portugaliae Electrochimica Acta. 2008;26(6):533–46.

    Article  CAS  Google Scholar 

  26. Umoren SA, Ebenso EE. Blends of polyvinyl pyrrolidone and polyacrylamide as corrosion inhibitors for aluminium in acidic medium. Indian J Chem Technol. 2008;15:355–63.

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Metallurgical and Materials Engineering, Colorado School of Mines, Golden, CO, USA

    Rahul Bhola, Shaily M. Bhola, Brajendra Mishra & David L. Olson

Authors
  1. Rahul Bhola
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Shaily M. Bhola
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Brajendra Mishra
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. David L. Olson
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Rahul Bhola.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Bhola, R., Bhola, S.M., Mishra, B. et al. Effect of povidone–iodine addition on the corrosion behavior of cp–Ti in normal saline. J Mater Sci: Mater Med 21, 1413–1420 (2010). https://doi.org/10.1007/s10856-010-4001-0

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10856-010-4001-0

Keywords

Search

Navigation