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X-ray methods to observe and quantify adhesive penetration into wood

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Abstract

To accelerate development of new and improved wood adhesives for engineered wood products, the optimal adhesive penetration into wood needs to be better understood for specific products and applications. Adhesive penetration includes both flow of adhesives into wood micron-scale voids and infiltration into the polymer components of the wood cell wall layers. In this work, X-ray computed tomography (XCT) and X-ray fluorescence microscopy (XFM) were used to study adhesive flow and infiltration. Model wood–adhesive bondlines were made using loblolly pine (Pinus taeda) latewood substrates and bromine-substituted phenol formaldehyde (BrPF) resins with different weight-average molecular weights (MW). The Br substitution facilitated both qualitative and quantitative observations using XCT and XFM. The BrPF resin flow into wood was visualized using XCT volume reconstructions and quantified by calculating the weighted penetration (WP). Examination of the shape of the cured BrPF–air interface in longitudinal tracheid lumina revealed that capillary action often played a role in BrPF flow. XFM mapping revealed the pathways of BrPF infiltration into the wood cell walls, and the results were used to calculate BrPF cell wall weight percent gain (WPGCW) in individual wood cell walls. Both WP and WPGCW decreased with increasing BrPF MW. Additionally, the middle lamella had higher WPGCW than its neighboring secondary cell walls, and within a given bondline the WPGCW decreased with increasing distance of the cell from the bondline. The results provide new insights that are needed in the development of improved models to understand and predict wood–adhesive bondline performance.

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Acknowledgements

This research used resources of the Advanced Photon Source, a US Department of Energy (DOE) Office of Science User Facility operated for the DOE Office of Science by Argonne National Laboratory under Contract No. DE-AC02-06CH11357.

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Authors and Affiliations

  1. Forest Biopolymers Science and Engineering, Forest Products Laboratory, USDA Forest Service, One Gifford Pinchot Drive, Madison, WI, 53726, USA

    Joseph E. Jakes, Charles R. Frihart, Christopher G. Hunt, Daniel J. Yelle, Nayomi Z. Plaza & Linda Lorenz

  2. Scion, 49 Sala Street, Private Bag 3020, Rotorua, 3046, New Zealand

    Warren Grigsby

  3. Wood Science and Engineering, Oregon State University, 119 Richardson Hall, Corvallis, OR, 97331, USA

    Daniel J. Ching & Fred Kamke

  4. Advanced Photon Source, Argonne National Laboratory, 9700 Cass Ave., Lemont, IL, 60439, USA

    Sophie-Charlotte Gleber, Stefan Vogt & Xianghui Xiao

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  1. Joseph E. Jakes
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  2. Charles R. Frihart
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  3. Christopher G. Hunt
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  12. Xianghui Xiao
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Correspondence to Joseph E. Jakes.

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Jakes, J.E., Frihart, C.R., Hunt, C.G. et al. X-ray methods to observe and quantify adhesive penetration into wood. J Mater Sci 54, 705–718 (2019). https://doi.org/10.1007/s10853-018-2783-5

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  • DOI: https://doi.org/10.1007/s10853-018-2783-5

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