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Rearrangement of cyclopropylborane into boretane

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Chemistry of Heterocyclic Compounds Aims and scope

Previously unknown boron-containing four-membered unsaturated heterocycle boretane was obtained via novel thermal rearrangement of cyclopropylborane and investigated by NMR and IR spectroscopy. Formation of boretane was also confirmed through its chemical transformation into more stable derivatives.

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  1. Department of Chemistry, University of Kansas and Center for Environmentally Beneficial Catalysis, 1251 Wescoe Hall Drive, Lawrence, KS, 66045, USA

    M. Rubina & M. Rubin

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  1. M. Rubina
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 5, 867-882, May, 2012.

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Rubina, M., Rubin, M. Rearrangement of cyclopropylborane into boretane. Chem Heterocycl Comp 48, 807–821 (2012). https://doi.org/10.1007/s10593-012-1060-9

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