Abstract
To reduce the thermal damage to the diamond and production cost, Cu-Sn-Ni-Cr and Cu-Sn-Cr were used to braze the diamond. SEM, EDS, and XRD were used to analyze the morphology of the diamond and the microstructure of the interface and the brazing alloy. Graphitization of the brazed diamond was tested by laser Raman, and the static compressive strength and toughness index of the diamond abrasive were measured. The results show that it realizes chemical metallurgical bonding between the diamond and either of these two filler metals, while Cu-Sn-Ni-Cr shows better wettability to the diamond. The brazed diamond has complete morphology and smoothing surface, there is almost no graphite in the diamond, but the static compressive strength and TI decrease slightly. On the surface of the diamond, it generates continuous laminar (Cr, Fe)7C3. The bonding strength between the diamond and the filler metal can meet the need of grinding. During the solidification process of the brazing alloy, dendrite α-Cu precipitates out firstly; then there is peritectic transformation and eutectoid transformation to form dendrite α-Cu, Cu6.5Sn, Cu9NiSn3, and eutectoid α-Cu.
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References
Chattopadhyay AK, Chollet L, Hintermann HE (1991) On performance of brazed monolayer diamond grinding wheel. CIRP Ann-manufacturing Technology 40:347–350
Sung CM (1999) Brazed diamond grid: a revolutionary design for diamond saws. Diam Relat Mater 8:1540–1543
Lee CH, Ham JO, Song MS, Lee CH (2007) The interfacial reaction between diamond grit and Ni-based brazing filler metal. Mater Trans 48(4):889–891
Ding WF, Xu JH, Chen ZZ, Yang CY, Song CJ, Fu YC (2013) Fabrication and performance of porous metal-bonded CBN grinding wheels using alumina bubble particles as pore-forming agents. Int J Adv Manuf Technol 67:1309–1315
Miao Q, Ding WF, Zhu YJ, Chen ZZ, Xu JH, Yang CY (2016) Joining interface and compressive strength of brazed cubic boron nitride grains with Ag-Cu-Ti/TiX composite fillers, 42(12): 13723–13737
Miao Q, Ding WF, Zhu YJ, Chen ZZ, Fu YC (2016) Brazing of CBN grains with Ag-Cu-Ti/TiX composite filler—the effect of TiX particles on microstructure and strength of bonding layer. Mater Des 98:243–253
Chen Y, Fu YC, Su HH, Xu JH, Xu HJ (2014) The effects of filler metal alloys on the morphologies and mechanical properties of brazed diamond grits. Int J Refract Met Hard Mater 42:23–29
Huang S, Liu X, Chen FZ, Zheng HX, Yang XL, Wu LB, Song JL, Xu WJ (2016) Diamond-cutting ferrous metals assisted by cold plasma and ultrasonic elliptical vibration. Int J Adv Manuf Technol 85:673–681
Duan DZ, Xiao B, Wang W, Zhang ZY, Wang B, Han P, Ding XY (2015) Interface characteristics and performance of pre-brazed diamond grains with Ni–Cr composite alloy. J Alloys Compd 644:626–631
Buhl S, Leinenbach C, Spolenak R, Wegener K (2012) Microstructure, residual stresses and shear strength of diamond–steel-joints brazed with a Cu–Sn-based active filler alloy. Int Journal of Refractory Metals and Hard Materials 30:16–24
Su HH, Dai JB, Ding WF, Zhang K, Xu W (2016) Experimental research on performance of monolayer brazed diamond wheel through a new precise dressing method—plate wheel dressing. Int J Adv Manuf Technol. doi:10.1007/s00170-016-8646-9
Ma BJ, Lian F (2013) Study on the use of CuSnTi brazing alloy for induction brazing of diamond grits surface-treated by direct current plasma chemical vapor deposition. Int J Refract Met Hard Mater 41:339–344
Ding WF, Miao Q, Xu JH (2013) Joining interface and grain fracture of single-layer brazed grinding wheels with binderless CBN grains. Int J Adv Manuf Technol 68(5–8):1261–1266
Ding WF, Zhu YJ, Xu JH, Fu YC (2015) Finite element investigation on the evolution of wear and stresses in brazed CBN grits during grinding. Int J Adv Manuf Technol 81:985–993
Ding WF, Xu JH, Chen ZZ, Fu YC, Su HH (2010) Relationship between embedding depth and residual stress in the cBN grain of monolayer brazed abrasive tools. J Mater Eng Perform 19(1):123–128
Zhou YM, Wang CY, Zhang FL, Xu ZC (2008) Cr powder-activated induction brazing of diamond grits with Ag–Cu–Zn alloy. Mater Manuf Process 23:352–356
Lu JB, Qi WC, Zhang WX, Li Y, Qi FJ, Zhong SJ, Xu S (2016) Effect of Cu-P-Sn on brazing diamond with Ni-based filler alloy. Int J Adv Manuf Technol. doi:10.1007/s00170-016-9400-z
Meng P (2016) Microstructure and performance of monolayer brazed grinding wheel with polycrystalline diamond grains. Int J Adv Manuf Technol 83:441–447
Gries T, Vandenbulcke L, Simon P, Canizares A (2008) Polarized micro-Raman spectroscopy for studying stresses in as-grown and tensile-tested diamond films. Surf Coat Technol 202:2263–2267
Sun BJ, Xiao B (2016) Mechanical properties of diamond grinding discs brazed in a continuous-belt tunnel furnace or vacuum furnace. Int J Adv Manuf Technol. doi:10.1007/s00170-016-9195-y
Hang CJ, Tian YH, Zhang R, Yang DS (2013) Phase transformation and grain orientation of Cu–Sn intermetallic compounds during low temperature bonding process. J Mater Sci Mater Electron 24:3905–3913
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Lu, Jb., Li, H., Li, Y. et al. Study on diamond vacuum brazed with Cu-based filler metal containing Cr. Int J Adv Manuf Technol 91, 1453–1460 (2017). https://doi.org/10.1007/s00170-016-9802-y
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DOI: https://doi.org/10.1007/s00170-016-9802-y