Abstract
Minimum ignition energies of hydrogen/air and methane/air mixtures have been investigated numerically by solving unsteady one-dimensional conservation equations with detailed chemical kinetic mechanisms. Initial kernel size needed for numerical calculation is a sensitive function of initial pressure of a mixture and should be estimated properly to obtain quantitative agreement with experimental results. A simple macroscopic model to determine minimum ignition energy has been proposed, where the initial kernel size is correlated with the quenching distance of a mixture and evaluated from the quenching distance determined from experiment. The simulation predicts minimum ignition energies of two sample mixtures successfully which are in a good agreement with the experimental data for the ranges of pressure and equivalence ratio.
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Abbreviations
- Ai :
-
Pre-exponential factor ini-th reaction step
- a:
-
Constant
- bi :
-
Temperature exponent ini-th reaction step
- Cp :
-
Constant-pressure specific heat
- Dj :
-
Diffusion coefficient of speciesj
- Ds :
-
Energy source density
- dq :
-
Quenching distance
- Eig :
-
Ignition energy
- Ei :
-
Activation energy ini-th reaction step
- h:
-
Specific enthalpy of mixture
- hj :
-
Specific enthalpy of speciesj
- ki :
-
Reaction rate constant ini-th reaction step
- n:
-
Exponent in Eq. (9)
- \(\bar M\) :
-
Mean molecular weight
- Mj :
-
Molecular weight of speciesj
- ns :
-
Number of species
- p:
-
Pressure
- \(\dot q\) :
-
Energy source
- \(\bar R\) :
-
Universal gas constant
- R0 :
-
Domain size
- r:
-
Spatial coordinate
- rs :
-
Radius of energy source (=initial kernel size)
- SL :
-
Burning velocity
- T:
-
Temperature
- t:
-
Time
- u:
-
Velocity
- Vc :
-
Correction factor for diffusion velocity
- Vo :
-
Mixture volume to be heated by supplied ignition energy
- Vj :
-
Diffusion velocity of speciesj
- X:
-
Mole fraction
- Y:
-
Mass fraction
- α:
-
Geometric factor
- δ:
-
Flame thickness
- Θj :
-
Thermal diffusion ratio of speciesj
- μ:
-
Viscosity of mixture
- λ:
-
Conductivity of mixture
- φ:
-
Equivalence ratio
- ϱ:
-
Density
- τrr, τθθ :
-
Stresses defined in Eq. (6)
- τ:
-
Duration of supplied energy
- wj :
-
Net production rate of speciesj
- o:
-
Initial state
- min:
-
Minimum
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Kim, H.J., Chung, S.H. & Sohn, C.H. Numerical Calculation of Minimum Ignition Energy for Hydrogen and Methane Fuels. KSME International Journal 18, 838–846 (2004). https://doi.org/10.1007/BF02990303
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DOI: https://doi.org/10.1007/BF02990303