Summary
Recent advances in the coupling of high-performance liquid chromatography with electrochemical detectors are discussed. Emphasis is laid on voltammetric detectors; new electrode materials and new excitation functions have lead to an enlarged field of applications, which hitherto were not accessible to the widely used oxidative amperometric detectors with carbon electrodes. Some non-inert metal electrodes and chemically modified electrodes are described in detail as well as pulsed amperometric detection and multiple electrode detectors. Various examples are given to illustrate the excellent selectivity of electrochemical detectors.
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References
H. Small, T. S. Stevens, W. C. Bauman, Anal. Chem.47, 1801 (1975).
Fachgruppe Wasserchemie in der Gesellschaft Deutscher Chemiker, “Deutsche Einheitsverfahren zur Wasser-, Abwasser- und Schlammuntersuchung”, VCH Verlagsgesellschaft, Weinheim, 1988; D 19.
F. Pal, E. Pungor, E. Kovats, Anal. Chem.60, 2254 (1988).
W. Kemula, Rocz. Chem.26, 281 (1952).
P. T. Kissinger, C. Refshauge, R. Dreiling, R. N. Adams, Anal. Lett.6, 465 (1973).
H. J. Bauch, E. Strüwer, U. Kelsch, Chromatographia28, 78 (1989).
W. Buchberger, J. Chromatogr.432, 57 (1988).
W. Buchberger, K. Winsauer, Mikrochim. Acta [Wien] 1980 II, 257.
K. Shimada, S. Orii, M. Tanaka, T. Nambara, J. Chromatogr.352, 329 (1986).
K. Shimada, T. Oe, M. Tanaka, T. Nambara, J. Chromatogr.487, 247 (1989).
R. Wintersteiger, G. Berliz, H. Springer, GIT Fachz. Lab.3/90, 286 (1990).
W. Buchberger, K. Winsauer, Ch. Breitwieser, Fresenius Z. Anal. Chem.315, 518 (1983).
G. Bonn, R. Concin, O. Bobleter, Wood Sci. Technol.17, 195 (1983).
W. Th. Kok, U. A. Th. Brinkman, R. W. Frei, J. Chromatogr.256, 17 (1983).
W. Th. Kok, G. Groenendijk, U. A. Th. Brinkman, R. W. Frei, J. Chromatogr.315, 271 (1984).
M. K. Halbert, R. P. Baldwin, Anal. Chem.57, 591 (1985).
L. M. Santos, R. P. Baldwin, Anal. Chem.58, 848 (1986).
L. M. Santos, R. P. Baldwin, Anal. Chem.59, 1766 (1987).
A. M. Tolbert, R. P. Baldwin, Electroanalysis,1, 389 (1989).
J. N. Barisci, G. G. Wallace, E. A. Wilke, M. Meaney, M. R. Smyth, J. G. Vos, Electroanalysis1, 245 (1989).
G. G. Wallace, M. Meaney, M. R. Smyth, J. G. Vos, Electroanalysis1, 357 (1989).
J. Wang, M. S. Lin, Electroanalysis1, 43 (1989).
M. P. Connor, J. Wang, W. Kubiak, M. R. Smyth, Anal. Chim. Acta229, 139 (1990).
Y. Ikariyama, W. R. Heineman, Anal. Chem.58, 1803 (1986).
Y. Ikariyama, Ch. Galiatsatos, W. R. Heineman, S. Yamauchi, Sens. Actuators12, 455 (1987).
D. C. Johnson, W. R. LaCourse, Anal. Chem.62, 589A (1990).
S. R. Müller, W. Simon, H. M. Widmer, G. Grolimund, G. Schomburg, P. Kolla, Anal. Chem.61, 2747 (1989).
P. R. Haddad, P. W. Alexander, M. Trojanowicz, J. Chromatogr.321, 363 (1985).
P. W. Alexander, P. R. Haddad, M. Trojanowicz, Chromatographia20, 179 (1985).
C. E. Cowie, P. R. Haddad, P. W. Alexander, Chromatographia21, 417 (1986).
P. R. Haddad, P. W. Alexander, M. Y. Croft, D. F. Hilton, Chromatographia24, 487 (1987).
E. Wang, H. Ji, Electroanalysis1, 75 (1989).
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Buchberger, W. Trends in the combination of high-performance liquid chromatography and electroanalytical methods. Chromatographia 30, 577–581 (1990). https://doi.org/10.1007/BF02269807
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DOI: https://doi.org/10.1007/BF02269807