Abstract
Uranium in aqueous solution can be extracted by sym-dibenzo-16-crown-5-oxy-acetic acid and its modified analogue 2-/sym-dibenzo-16-crown-5-oxy/-hexanoic acid into chloroform in the pH range 5.5–6.0. The extraction method combined with neutron activation analysis provides a sensitive method for the determination of uranium in natural waters.
Similar content being viewed by others
References
C.J. Pedersen,J. Am. Chem. Soc., 89 /1967/ 7017.
M. Tagaki, H. Nakamura,J. Coord. Chem., 15 /1986/ 53.
J. Tang, C.M. Wai,Anal. Chem., 58 /1986/ 3233.
R.A. Bartsch, G.S. Heo, S.I. Kang, Y. Liu, J. Strzelbicki,J. Org. Chem., 47 /1982/ 457.
Water Analysis by Atomic Absorption, Varian Techtron Pty, Ltd., Palo Alto, CA, 1972.
J. Strzelbicki, R.A. Bartsch,Anal. Chem., 53 /1981/ 1894.
C.F. Baes, Jr., R.E. Mesmer, The Hydrolysis of Cations, J. Wiley and Sons, N.J., 1976, p. 177.
W.M. Mok, H. Willmes, C.M. Wai,Radiochem. Radioanal. Lett., 59 /1983/ 329.
F.B. Barker, R.C. Scott, U.S. Geol. Surv. Profess. Papers 424-B, 1961, 298.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Tang, J., Wai, C.M. Extraction of uranium with crown ether carboxylic acids for neutron activation analysis. Journal of Radioanalytical and Nuclear Chemistry Letters 128, 61–69 (1988). https://doi.org/10.1007/BF02167026
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF02167026