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Intramolecular cyclization of Z,E,E-1,5,9,-cyclododecatriene by the Cp2TiCl2−LiAlH4 system

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Abstract

The system Cp2TiCl2−LiAlH4, in the absence of ethereal solvents, catalyzes the intramolecular cyclization of Z,E,E-1,5,9-cyclododecatriene, yielding a mixture of C12 hydrocarbons consisting mainly of cis, anti, cis-and cis, syn, trans-tricyclo [7.3.0.02,6] dodec-7-ene and 5,6,7,8,9,10-hexahydrobenzocyclooctene.

Abstract

Система Cp2TiCl2−LiAlH4, в отсутствии эфирных растворителеь, катализирует внутримолекулярную циклизацию Z,E,E,-1,5,9-циклододекатриена, давая смесь углеводородов C12, состоящих преимущественно из цис, анти, цис-и цис, син, транс-трицикло [7.3.0.0.2,6] додекена-7, и 5,6,7,8,9,10-гексагидробензоциклооктена.

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Authors and Affiliations

  1. J. Heyrovský Institute of Physical Chemistry and Electrochemistry, Czechoslovak Academy of Sciences, 121 38, Prague 2, Czechoslovakia

    H. Antropiusová, K. Mach, V. Hanuš & F. Tureček

  2. Microbiological Institute, Czechoslovak Academy of Sciences, 142 20, Prague 4, Czechoslovakia

    P. Sedmera

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  1. H. Antropiusová
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  2. K. Mach
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  3. V. Hanuš
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  4. F. Tureček
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  5. P. Sedmera
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Antropiusová, H., Mach, K., Hanuš, V. et al. Intramolecular cyclization of Z,E,E-1,5,9,-cyclododecatriene by the Cp2TiCl2−LiAlH4 system. React Kinet Catal Lett 10, 297–300 (1979). https://doi.org/10.1007/BF02075311

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  • DOI: https://doi.org/10.1007/BF02075311

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