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The synthesis and crystal structure of [La(OH2)5(phen)2]Cl3·4H2O·phen

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[La(OH2)5(phen)2]Cl3·4H2O·phen is centric, Pnna, witha=19.946(7),b=16.458(5),c=12.207(4)Å andD calc=1.57 g cm−3 forZ=4. The La(III) ion resides on a crystallographic twofold axis and is coordinated to four nitrogen atoms (from two phen molecules) and five water molecules resulting in a distorted tricapped trigonal prismatic geometry. An uncoordinated phen molecule, two chloride anions, and four uncoordinated water molecules are hydrogen bonded to the coordinated water molecules. The coordinated and uncoordinated phen molecules π-stack diagonally through the unit cell.

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Authors and Affiliations

  1. Department of Chemistry, Wuhan University, 430072, Wuhan, China

    Zhen Ping Ji

  2. Laboratory of Rare Earth Chemistry and Physics, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, Chinese

    Zhen Ping Ji

  3. Department of Chemistry, Northern Illinois University, 60115, Illinois, DeKalb

    Robin D. Rogers

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  1. Zhen Ping Ji
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  2. Robin D. Rogers
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Ji, Z.P., Rogers, R.D. The synthesis and crystal structure of [La(OH2)5(phen)2]Cl3·4H2O·phen. J Chem Crystallogr 24, 797–800 (1994). https://doi.org/10.1007/BF01668243

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  • DOI: https://doi.org/10.1007/BF01668243

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