Abstract
The crystal and molecular structure of catena-[(μ-acetato) (μ-phthalazine)-silver(I)dihydrate], {[Ag(O2CCH3) (C8H6N2)(H2O)2]2}n, has been determined by single crystal X-ray analysis: the space group is P21/n,a=16.150(8) Å,b=3.886(5) Å,c=18.716(9) Å, β=96.02(5)°,V=1168 Å3. Phthalazine (PHZ) bridges the silver atoms to form {Ag-μ-PHZ]2 dimeric subunits. These dimeric subunits are planar and stack by bridging acetates to form a polymeric lattice. The acetates also form an asymrnetric chelate ring with the silver atoms which result in a distorted, square pyramidal configuration. The complex is further characterized by its IR and thermal properties.
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Whitcomb, D.R., Rogers, R.D. The properties, crystal, and molecular structure of catena-[(μ-acetato-) (μ-phthalazine)silver(I)dihydrate]: {[Ag(μ-O2CCH3) (μ-PHZ) (H2O)2]2}n . J Chem Crystallogr 25, 137–142 (1995). https://doi.org/10.1007/BF01665989
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DOI: https://doi.org/10.1007/BF01665989