Abstract
It is proposed that a number of the high-frequency far-infrared (FIR) laser lines observed when CH3OH is optically pumped by high-power CO2 TEA lasers can be identified as refilling torsional transitions within the vibrational ground state. Assignments are presented for 8 such TEA-pump/FIR-laser refilling systems. To provide support for the assigned laser frequencies, high-resolution Fourier transform FIR spectra of CH3OH have been obtained and partially analyzed in the torsional transition region.
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Mukhopadhyay, I., Lees, R.M. & Johns, J.W.C. Torsional refilling transitions in tea-pumped CH3OH fir lasers with associated high-resolution fir spectra. Int J Infrared Milli Waves 8, 1471–1482 (1987). https://doi.org/10.1007/BF01117773
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DOI: https://doi.org/10.1007/BF01117773