Summary
Equimolar adducts of mononuclear oxomolybdenum(IV)O,O′-dialkyl and alkylene dithiophosphates with heterocyclic amines, MoO[S2P(OR)2]2·L (where when R=Et,i-Bu; L=pyridine and when R=Et,n-Pr,i-Bu; L=2,2′-bipyridyl, 1,10-phenanthroline) and
(where G=CH2CMe2CH2, L=2,2′-bipyridyl and when G=CMe2CMe2; L=pyridine) have been prepared by reacting the corresponding oxomolybdenum(IV) complexes with an excess of pyridine or with bipyridyl or phenanthroline in a 1∶1 molar ratio.
The complexes have been characterized by elemental analyses and molecular weight determinations. Their probable structures are proposed on the basis of i.r. and n.m.r. (1H,13C and31P) spectral data, which are consistent with a 6-coordinated octahedral structure for all the base adduct complexes.
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Ratnani, R., Srivastava, G. & Mehrotra, R.C. Adducts of mononuclear oxomolybdenum(IV)O,O′-dialkyl(alkylene) dithiophosphate complexes with pyridine, 2,2′-bipyridyl and 1, 10-phenanthroline. Transition Met Chem 16, 204–208 (1991). https://doi.org/10.1007/BF01032835
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DOI: https://doi.org/10.1007/BF01032835