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Fluordiazadiphosphetidine, 17. Mitt.

Fluordiazadiphosphetidines, 17: Reaction of (CH3NPF3)2 and F3P(CH3N)2PF2OCH3 with lithium-1,1,1-trimethyl-N-(trimethylsilyl)-silanamide

Die Reaktion von 2,2,2,4,4,4-Hexafluor-1,3-dimethyl-1,3,2λ5, 4λ5-diazadiphosphetidin und von 2,2,2,4,4-Pentafluor-4-methoxy-1,3-dimethyl-1,3,2λ5, 4λ5-diazadi-phosphetidin mit Lithium-1,1,1-trimethyl-N-(trimethylsilyl)-silanamid

  • Anorganische Und Physikalische Chemie
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Monatshefte für Chemie / Chemical Monthly Aims and scope Submit manuscript

Abstract

The reactions of (CH3NPF3)2 and F3P(CH3N)2PF2OCH3 with lithium-1,1,1-trimethyl-N-(trimethylsilyl)-silanamide yield two new dispiro-compounds:XF2P(CH3N)2PF(NSiCH3)2PF(CH3N)2PF2 X withX=F, OCH3. Synthesis, mass-spectra and X-ray structures are discussed.

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Authors and Affiliations

  1. Institut für Anorganische Chemie, Technische Universität Wien, A-1060, Wien, Österreich

    Kurt Utvary & Klaus Galle

  2. Department of Chemistry, University of Texas, Austin, Texas, USA

    Alan Cowley & Atta Arif

Authors
  1. Kurt Utvary
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  2. Klaus Galle
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  3. Alan Cowley
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  4. Atta Arif
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Additional information

Herrn Prof. Dr.K. L. Komarek zum 60. Geburtstag gewidmet.

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Utvary, K., Galle, K., Cowley, A. et al. Fluordiazadiphosphetidine, 17. Mitt.. Monatsh Chem 117, 1245–1256 (1986). https://doi.org/10.1007/BF00810869

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  • DOI: https://doi.org/10.1007/BF00810869

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