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Use of ethyl oxamate for syntheses of oxamato(-1) and novel μ-oxamato(-2) complexes

Der Einsatz von Ethyloxamat für die Synthese von Oxamato(-1) und neuen μ-Oxamato(-2)-Komplexen (Kurze Mitt.)

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  • Organische Chemie Und Biochemie
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Summary

The use of ethyl oxamate for the synthesis of inorganic oxamato complexes is reported. A reaction system leading to the preparation of the novel polymeric μ-oxamato(-2) complexes [M(oxm)(H2O)2] x (M=Cu, Zn, Cd), [Co(oxm)(H2O)2] x ·0.5xH2O and [Ni(oxm)(H2O)2] x ·xH2O is described (H2 oxm = oxamic acid). Ethyl oxamate can also be used for the preparation of monomeric oxamato(-1) complexes.

Zusammenfassung

Es wird der Einsatz von Ethyloxamat für die Synthese von anorganischen Oxamato-Komplexen beschrieben. Ein Reaktions-System für die Herstellung von neuen μ-Oxamato(-2)-Komplexpolymeren: [M(oxm)(H2O)2] x ; (M = Cu, Zn, Cd), [Co(oxm)(H2O)2] x ·0.5xH2O und [Ni(oxm)(H2O)2] x ·xH2O, wird vorgestellt. Ethyloxamat kann auch für die Herstellung von monomeren Oxamato(-1)-Komplexen verwendet werden.

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Author notes

  1. Spyros P. Perlepes

    Present address: Department of Chemistry, Indiana University, 47405, Bloomington, IN, USA

Authors and Affiliations

  1. Department of Chemistry, University of Ioannina, GR-45110, Ioannina, Greece

    Panayotis Th. Veltsistas, Spyros P. Perlepes, Miltiadis I. Karayannis & John M. Tsangaris

Authors
  1. Panayotis Th. Veltsistas
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  2. Spyros P. Perlepes
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  3. Miltiadis I. Karayannis
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  4. John M. Tsangaris
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Veltsistas, P.T., Perlepes, S.P., Karayannis, M.I. et al. Use of ethyl oxamate for syntheses of oxamato(-1) and novel μ-oxamato(-2) complexes. Monatsh Chem 121, 703–707 (1990). https://doi.org/10.1007/BF00809776

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  • DOI: https://doi.org/10.1007/BF00809776

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