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Unexpected products of the allyldiethylamine hydroformylation homogeneously catalyzed by rhodium complexes

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Abstract

Attempts to carry out the hydroformylation of allyldiethylamine homogeneously catalyzed by rhodium complexes led to unexpected formation of N,N,N′,N′-tetraethyl-1,4-diaminobutane and 4-(diethylamino)-1-butanole as final products. The role of the catalyst on the product formation and the reaction mechanism are briefly discussed.

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Authors and Affiliations

  1. Research Unit, Galena Co., Branišovská 31, 37005, České Budějovice, Czech Republic

    Alexandr Jegorov

  2. Department of Organic Chemistry, Charles University, 128 40, Prague 2, Czech Republic

    Tomáš Trnka

  3. Department of Chemistry BG 10, University of Washington, WA98195, Seattle, USA

    František Tureček

  4. Institute of Physical Chemistry, Czech Academy of Sciences, 18223, Prague, Czech Republic

    Vladimír Hanuš

Authors
  1. Alexandr Jegorov
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  2. Tomáš Trnka
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  3. František Tureček
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  4. Vladimír Hanuš
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Jegorov, A., Trnka, T., Tureček, F. et al. Unexpected products of the allyldiethylamine hydroformylation homogeneously catalyzed by rhodium complexes. Catal Lett 18, 261–264 (1993). https://doi.org/10.1007/BF00769445

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  • DOI: https://doi.org/10.1007/BF00769445

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