Abstract
The glassy behaviour of the thermal conductivities of structure I xenon and structure II hydrate at high temperature are found to be described surprisingly well by a localized oscillator model. This observation leads to the suggestion of strong coupling between the localized vibrations of the guest with the lattice acoustic phonons. This conjecture is confirmed by a phenomenological calculation using the Anderson-Fano resonant scattering model.
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Tse, J.S. Localized oscillators and heat conduction in clathrate hydrates. J Incl Phenom Macrocycl Chem 17, 259–266 (1994). https://doi.org/10.1007/BF00708785
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DOI: https://doi.org/10.1007/BF00708785