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Neutral solvent/crown ether interactions, 4. Crystallization and low temperature (−150°C) structural characterization of 18-crown-6 · 2(CH3CN)

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Abstract

The crystal structure of 18-crown-6 · 2(CH3CN) has been determined via data collection at −150°C. The structure consists of two crown molecules each hydrogen bonded to two acetonitrile moieties in the asymmetric unit, each residing around a center of inversion. The crown ethers display their fullD 3d symmetry; methyl ... O contacts range from 3.189(8) to 3.598(8) Å. There are no close contacts indicative of any interaction between the crown/2(CH3CN) units.

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References

  1. Part 3:R. D. Rogers and P. D. Richards:J. Incl. Phenom. 5, 631 (1987).

    Google Scholar 

  2. F. Vögtle and E. Weber (eds.).Host Guest Complex Chemistry Macrocycles Synthesis, Structures, Applications, Springer-Verlag, Berlin (1985).

    Google Scholar 

  3. R. D. Rogers and L. M. Green:J. Incl. Phenom. 4, 77 (1986) and references therein.

    Google Scholar 

  4. A. van Zon, F. de Jong, D. N. Reinhoudt, G. J. Torny, and Y. Onwezen:Recl. Trav. Chim. Pays-Bas 100, 453 (1981).

    Google Scholar 

  5. H. M. Colquhoun, J. F. Stoddart, and D. J. Williams:J. Am. Chem. Soc. 104, 1426 (1982).

    Google Scholar 

  6. R. D. Rogers, L. K. Kurihara, and M. M. Benning:J. Incl. Phenom. 5, 645 (1987).

    Google Scholar 

  7. B. L. Allwood, S. E. Fuller, P. C. Y. K. Ning, A. M. Z. Slawin, J. F. Stoddart, and D. J. Williams:J. Chem. Soc., Chem. Commun. 1356 (1984).

  8. Part 16: R. D. Rogers:Inorg. Chim. Acta, in press (1987).

  9. R. D. Rogers, L. K. Kurihara, and P. D. Richards:J. Chem. Soc., Chem. Commun., 604 (1987).

  10. G. Weber,J. Mol. Struct. 98, 333 (1983).

    Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, Northern Illinois University, 60115, DeKalb, IL, USA

    Robin D. Rogers, Philip D. Richards & Eric J. Voss

Authors
  1. Robin D. Rogers
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  2. Philip D. Richards
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  3. Eric J. Voss
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Additional information

Supplementary Data relating to this article are deposited with the British Library as Supplementary Publication No. SUP 82056 (14 pages).

For Part 3, see reference [1]

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Rogers, R.D., Richards, P.D. & Voss, E.J. Neutral solvent/crown ether interactions, 4. Crystallization and low temperature (−150°C) structural characterization of 18-crown-6 · 2(CH3CN). Journal of Inclusion Phenomena 6, 65–71 (1988). https://doi.org/10.1007/BF00659370

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  • DOI: https://doi.org/10.1007/BF00659370

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