Summary
A series of [L′2TiL]+X−compounds where L is the conjugate base of acetylacetone, L′=η-MeC5H4 and X−= ClO −4 , BF −4 , FeCl −4 , ZnCl3(H2O)−, SnCl −3 , CdCl 2−4 , HgCl 2−4 , Br− or I−, have been prepared by adding X− to the aqueous solution of [L′2TiL]+Cl−. Conductivity measurements in nitrobenzene for all compounds indicate that these complexes are electrolytes. The i.r. frequencies for various vibrational modes have been assigned. The ligand L appears to be chelating and the titanium atom is essentially tetracoordinate. The bonding in these complexes is discussed.
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On study leave from S. D. College, Muzaffar Nagar, U.P., India.
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Chandra, K., Sharma, R.K., Garg, B.S. et al. The preparation and characterization of acetylacetonato-bis(η-methylcyclopentadienyl)titanium(IV) complexes. Transition Met Chem 4, 367–371 (1979). https://doi.org/10.1007/BF00623979
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DOI: https://doi.org/10.1007/BF00623979