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Pulse Induced Critical Scattering from solutions of randomly crosslinked polystyrene in cyclohexane

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Summary

The spinodal decomposition was observed by the Pulse Induced Critical Scattering technique for the three branched polystyrenes in cyclohexane. Branched polystyrenes were prepared by γ-irradiation on linear polystyrene of narrow molar-mass distribution for various periods. The location of the spinodals was hardly affected with regard to temperature though the crosslinking has increased the molar mass by a factor 10.

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Authors and Affiliations

  1. Institut für makromolekulare Chemie der Universität Freiburg, Stefan-Meier-Str. 31, D-7800, Freiburg i. Br., Federal Republic of Germany

    K. Kajiwara & W. Burchard

  2. DSM Research and Patents, NL-6160, MD Geleen, Netherlands

    L. A. Kleintjens & R. Koningsveld

Authors
  1. K. Kajiwara
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  2. W. Burchard
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  3. L. A. Kleintjens
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  4. R. Koningsveld
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Kajiwara, K., Burchard, W., Kleintjens, L.A. et al. Pulse Induced Critical Scattering from solutions of randomly crosslinked polystyrene in cyclohexane. Polymer Bulletin 7, 191–195 (1982). https://doi.org/10.1007/BF00255314

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  • DOI: https://doi.org/10.1007/BF00255314

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