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Transition metal complexes with neutral and deprotonated malonamide

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Summary

New complexes of the general formulae [M(LH2)2Cl2] (M = Mn, Fe, Co, Ni, Cu, Zn), [Mn(LH2)2X2] (X = Br, I), [Cu(LH2)2Br2], [Ni(LH2)2X2] (X = Br, NCS, ONO2), [Cu(LH2)X2]n (X = Cl, Br), K2[NiL2]·2H2O and K2-[CuL2]·H2O, where LH2 = malonamide, were isolated. The complexes were characterized by elemental analyses, X-ray powder patterns, magnetic susceptibilities and spectroscopic (variable-temperature 57Fe-Mössbauer, e.s.r., u.v.-vis., i.r., far-i.r., Raman) studies. Monomeric trans pseudo-octahedral stereochemistries for the neutral 1∶2 complexes and square planar structures of D 2h symmetry for the two ionic complexes are assigned in the solid state. Dimeric or polymeric five-coordinate structures are proposed for the 1∶1 copper(II) compounds. LH2 and L2− behave as bidentate chelating ligands binding through oxygen and deprotonated nitrogen atoms, respectively. A detailed comparison of the studied complexes with the corresponding oxamide complexes is also presented.

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Authors and Affiliations

  1. Laboratorium Anorganische Scheikunde, Universitair Centrum Antwerpen, Groenenborgerlaan 171, 2020, Antwerpen, Belgium

    Sabrina De Beukeleer & Herman O. Desseyn

  2. Department of Chemistry, University of Patras, 26010, Patra, Greece

    Spyros P. Perlepes & Evy Manessi-Zoupa

Authors
  1. Sabrina De Beukeleer
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  2. Herman O. Desseyn
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  3. Spyros P. Perlepes
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  4. Evy Manessi-Zoupa
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De Beukeleer, S., Desseyn, H.O., Perlepes, S.P. et al. Transition metal complexes with neutral and deprotonated malonamide. Transition Met Chem 19, 468–476 (1994). https://doi.org/10.1007/BF00139331

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