Abstract
Galvanic contact, occurring between electrically conducting minerals in flotation pulps, may affect the nature of mineral surfaces and influence their floatabilities. Rest potential and galvanic current measurements were made on an electrode combination of pyrite and pyrrhotite under nitrogen, air and oxygen aeration conditions. The results were correlated with their oxygen-consuming characteristics and flotation behaviors. The galvanic contact improved the floatability of pyrrhotite, but adversely affected that of pyrite. Auger electron spectroscopy, X-ray photoelectron spectroscopy, and scanning electron microscopy indicated that the formation of hydroxide or oxide and sulfate species of iron on pyrrhotite decreased, whereas that on pyrite increased when these minerals were held in contact. An electrochemical mechanism was proposed for the observed behaviors.
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Adam, K., 1983, “Grinding Media Corrosion and Its Effect on Flotation of Sulfide Minerals,” PhD thesis, University of Minnesota.
Adam, K., and Iwasaki, I., 1984, “Effects of Polarization on the Surface Properties of Pyrrhotite,” Minerals and Metallurgical Processing, Vol. 1, pp. 246–253.
Adam, K., Natarajan, K.A., and Iwasaki, I., 1984, “Grinding Media Water and Its Effect on the Flotation of Sulfide Minerals,” International Journal of Mineral Processing, Vol. 12, pp. 39–54.
Bancroft, G.M., Adams, I., Coatsworth, L., Bennewitz, C.D., and Brown. J.D., 1975 “ESCA Study of Sputtered Platinum Films,” Anal. Chem., Vol. 47, pp. 586–588.
Buckley, A.N., and Woods, R., 1984, “An X-ray Photoelectron Spectroscopic Investigation of the Surface Oxidation of Sulfide Mineral,” Electrochemistry in Mineral and Metal Processing, P.E. Richardson, S. Srinivasan, and R. Wood, eds., the Electrochemical Society Inc., Pennington, NJ, pp. 286–302.
Chang, C.S., Cooke, S.R.B., and Iwasaki, I., 1954, “Flotation Characteristics of Pyrrhotite and Xanthates,” Trans. AIME, Vol. 199, pp. 209–217.
Clifford, R.K., Purdy, K.L., and Millar, J.D., 1975, “Characterization of Sulfide Mineral Surface in Froth Flotation Systems Using Electron Spectroscopy for Chemical Analysis,” AlChE Symposium Series, Vol. 150, No. 71, pp. 138–147.
Foster, L.S., 1928, “Preparation of Xanthates and Other Organic Thiocarbonates,” Utah Engineering Experimental Station, T.P.2.
Gardner, J.R., and Woods, R., 1977, “An Electrochemical Investigation of Contact Angle and of Flotation in the Presence of Alkylxanthates II,” Australian Journal of Chemistry, Vol. 30, pp. 981–991.
Gottschalk, V.H., and Buehler, H.A., 1912, “Oxidation of Sulfides,” Economic Geology, Vol. 15, pp. 15–34.
Hamilton, C., and Woods, R., 1981, “An Investigation of Surface Oxidation of Pyrite and Pyrrhotite by Liner Potential Sweep Voltammetry,” Journal of Electroanalytial Chemistry, Vol. 118, pp. 327–343.
Hiskey, J.B., and Wadsworth, M.E., 1975, “Galvanic Conversion of Chalcopyrite.” Met. Trans., Vol. 6B, pp. 183–190.
Ishihara, T., and Kagami, Y., 1964, “The Effect of Aeration and Oxidation of Pyrrhotite on Flotation,” Nippon Kogyokaishi, Vol. 80, pp. 881–886.
Janetski, N.D., Woodburn, S.I., and Woods, R., 1977, “An Electrochemical Investigation of Pyrite Flotation and Depression,” International Journal of Mineral Processing, Vol. 4, pp. 227–239.
Kuhn, A.T., and Chan, C.Y., 1983, “pH Changes at Near-Electrode Surface” Applied Electrochemistry, Vol. 13, pp. 187–207.
Learmont and Iwasaki, 1984, “Effect of Grinding Media on Galena Flotation,” Minerals and Metallurgical Processing, Vol. 1, pp. 136–143.
Majima, H., 1969, “How Oxidation Affects Selective Flotation of Complex Sulfide Ore,” Canadian Metallurgical Quarterly, Vol. 8, pp. 269–273.
Mizoguchi, T., and Habashi, F., 1983, “Aqueous Oxidation of Zinc Sulphide, Pyrite, and Their Mixtures in Hydrochloric Acid,” Trans. Institute of Mining and Metallurgy, Vol. 92, pp. C14–19.
Pavlica, J.J., and Iwasaki, I., 1982, “Electrochemical and Magnetic Interactions in Pyrrhotite Flotation,” Trans. SME-AIME, Vol. 272, pp. 1885–1889.
Rao, S.R., Moon, K.S., and Leja, J., 1979, “Effect of Grinding Media on Surface Reactions and Flotation of Heavy Metal Sulfide,” Flotation, A.M. Gaudin Memorial Volume, Vol 1., M.C. Fuerstenau, ed., AIME, New York, NY, pp. 509–527.
Schultz, H.D., and Proctor, W.G., 1973, “Application of Electron Emission Spectroscopy to Characterize Sulfur Bonds in Coal,” Applied Spectroscopy Vol. 27, pp. 347–351.
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SME preprint 85-25, SME-AIME Annual Meeting, New York, NY, February 1985. MMP paper 85-605. Manuscript November 1984. Discussion of this paper must be submitted, in duplicate, prior to Jan. 31, 1986.
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Nakazawa, H., Iwasaki, I. Effect of pyrite-pyrrhotite contact on their floatabilities. Mining, Metallurgy & Exploration 2, 206–211 (1985). https://doi.org/10.1007/BF03402621
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DOI: https://doi.org/10.1007/BF03402621