Summary
The marked solubility of coumarin in aqueous mineral acids is attributed to the formation of complexes. That this takes place through hydrogen bonds is shown by a study of the Raman spectrum of these solutions wherein the carbonyl frequency is found to be considerably lowered, but still persists.
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Murty and SesiradriProc. Iad. Acad. Sci., A, 1942,15, 157.
—Ibid., 1941,14, 601.
—Ibid., 1942,15, 241.
—Ibid., 1939,10, 315.
—Ibid., 1941,14, 598; 1938,8, 520.
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Murty, G.V.L.N., Seshadri, T.R. Raman effect and Hydrogen Bonds. Proc. Indian Acad. Sci. (Math. Sci.) 17, 55–57 (1943). https://doi.org/10.1007/BF03053041
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DOI: https://doi.org/10.1007/BF03053041