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N.M.R. and I.R. studies of 1, 1, 1 trifluoroacetone in proton donor solvents

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Abstract

Interactions of 1, 1, 1 trifluoroacetone with proton donor solvents of the type RH [where R=HO, CH3S, CH3CH2CH2CH2S, CH3O, (CH3)2N, (C2H5)2N] have been investigated using NMR and infra-red techniques. Evidence of the formation of addition products of the type CF3.C(OH)R.CH3 where OH group is hydrogen-bonded with the fluorine of the CF3 group has been obtained.

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Authors and Affiliations

  1. Tata Institute of Fundamental Research, Bombay-5

    C. L. Khetrapal, M. M. Dhingra & V. B. Kartha

  2. Bhabha Atomic Research Centre, Bombay

    C. L. Khetrapal, M. M. Dhingra & V. B. Kartha

Authors
  1. C. L. Khetrapal
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  2. M. M. Dhingra
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  3. V. B. Kartha
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Additional information

Communicated by Prof. B. V. Thosar,f.a.sc.

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Khetrapal, C.L., Dhingra, M.M. & Kartha, V.B. N.M.R. and I.R. studies of 1, 1, 1 trifluoroacetone in proton donor solvents. Proc. Indian Acad. Sci. 66, 196–200 (1967). https://doi.org/10.1007/BF03050736

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  • DOI: https://doi.org/10.1007/BF03050736

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