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The Raman and infra-red spectra of some solid hydroxides

Part II. Correlation with crystal structure

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5. Summary

The paper discusses the results reported in Part I in relation to the crystal structures of the substances. From a comparison of the facts with the theoretically expected picture of the spectrum, the salient features exhibited by the spectra have been explained, in addition to identification and assignment of the frequencies wherever feasible. The progressive variations in the hydroxyl shifts exhibited by the different hydroxides and their hydrates are explicable as due to the interactions of the hydroxyls with each other and also with their neighbouring water molecules in the case of the hydrates.

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6. References

  1. Ernst, T...Zeit. Physik. Chem., 1933,20 B, 65.

    Google Scholar 

  2. Pepinsky, R...Phys. Rev., 1939,55, 1115. (See alsoStrukturbericht, Band VII, 1939, pp. 4et seq.).

    Google Scholar 

  3. Ernst, T...Angew. Chem., 1948,60 A, 77.

    Google Scholar 

  4. Busing, W. R...J. Chem. Phys., 1955,23, 933.

    Article  Google Scholar 

  5. Wunderlich, J. A...Bull. Soc. Fran. Miner., Crist., 1958,81, 287.

    Google Scholar 

  6. Clastre, J...Acta Cryst., 1954,7, 638.

    Google Scholar 

  7. Bragg, W. L. ..Atomic Structure of Minerals, Oxford University Press (1937), pp. 108.

  8. Busing, W. R. and Levy, H. A.J. Chem. Phys., 1957,26, 563.

    Article  Google Scholar 

  9. Petch, H. E...Canad. Jour. Phys., 1957,35, 983.

    Google Scholar 

  10. Smith, H. G...Acta Cryst., 1953,6, 604.

    Article  Google Scholar 

  11. Ramaseshan, S. .. Private communication.

  12. Megaw, H. D...Zeit. Krist., 1934,87, 185.

    Google Scholar 

  13. Bhagavantam, S...Proc. Ind. Acad. Sci., 1941,13 A, 543.

    Google Scholar 

  14. Levy, H. A. and Peterson, S. W.Rev. Mod. Phys., 1958,30, 101.

    Article  Google Scholar 

  15. Bernal, J. D. and Megaw, H. D.Proc. Roy. Soc., 1935,151 A, 384.

    Google Scholar 

  16. Partington, J. R...General and Inorganic Chemistry, McMillan & Co., London, 1958, pp. 322.

    Google Scholar 

  17. Krishnamurti, D...Proc. Ind. Acad. Sci., 1959,50 A, 223.

    Google Scholar 

  18. Wilson, E. B.,et al. ..Molecular Vibrations, McGraw-Hill Book Co., 1955.

  19. Herzberg, G. ..Infra-red and Raman Spectra of Polyatomic Molecules, D. Van Nostrand Co., Inc., 1945, pp. 280et seq.

  20. Bhagavantam, S. and Venkatarayudu, T.Theory of Groups and Its Application to Physical Problems, Andhra University, Waltair, 1948.

    Google Scholar 

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Authors
  1. D. Krishnamurti F.A.Sc.
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Additional information

Memoir No. 119from the Raman Research Institute, Bangalore-6

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Krishnamurti, D. The Raman and infra-red spectra of some solid hydroxides. Proc. Indian Acad. Sci. 50, 232–246 (1959). https://doi.org/10.1007/BF03048859

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  • DOI: https://doi.org/10.1007/BF03048859

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