Abstract
Sulphate glasses are typical ionic glasses in the sense they are constituted of discrete anions. In this review various physical properties of K2SO4, Na2SO4 and ZnSO4 glasses have been reported. A model of random close packing of ions has been suggested and used to interpret several properties including the origin of mixed alkali effect.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Angell C A and Helphrey D 1971J. Phys. Chem. 7523
Bates 1960 inModern aspects of vitreons states ed J D Mackenzie (London: Butterworths)3
Bernal J D 1965Liquids, structures, properties, solid interactions ed T T Hughel (Amsterdam: Elsevier)
Cargill G S 1975Solid state physics eds H Ehrenreich, F Seitz and D Tunbull (New York: Academic Press)30 227
Gattow G and Zemann J 1958Z. Anorg. Allg. Chem. 293 233
Glass A M, Lines M E, Nassan K and Shierer J W 1977Appl. Phys. Lett. 31 249
Johari G P and Goldstein M 1970J. Chem. Phys. 53 2372
Miller P J 1979J. Chem. Phys. 71 997
Narasimham P S L and Rao K J 1978aJ. Non-Cryst. Solids 27 225
Narasimham P S L and Rao K J 1978bProc Indian Acad. Sci. (Chem. Sci.) A87 275
Narasimham P S L and Rao K J 1979aBull. Mater. Sci. 1 71
Narasimham P S L, Mahadevan S and Rao K J 1979bProc. Indian Acad. Sci. (Chem. Sci.) A88 11
Polk D E 1970Scripta Met. 4 117
Polk D E 1972Acta Metall. 20 485
Rao K J, Helphrey D and Angell C A 1973Phys. Chem. Glasses 14 26
Rao K J and Sundar H G K 1980Phys. Chem. Glasses 21 216
Sunder H G K and Rao K J 1980J. Chem. Soc. Faraday Trans. I Chem. 76 1617
Yamane M and Mackenzie J D 1974J. Non-Cryst. Solids 15 153
Author information
Authors and Affiliations
Additional information
Communication No.78 from Solid State and Structural Chemistry Unit.
Rights and permissions
About this article
Cite this article
Rao, K.J. Ionic sulphate glasses. Bull. Mater. Sci. 2, 357–380 (1980). https://doi.org/10.1007/BF02908581
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF02908581