Abstract
It is studied that Rhus vernicifera laccase catalyzed oxidation of 26 disubstituted ferrocene and its metal complexes, π-arene-π-cyclopentadienyliron derivatives and metal meso-(tetra-4-sulfanatophenyl)porphyrin in the diethylene glycol monobutyl ether (DGBE)/phosphate buffer (V/V, 1/5). It is found that 1,1′-bishydroxylmethyl ferrocene etc 16 compounds are new substrates of laccase. The relation of structure and function of substrates is discussed. The affective factors of laccase-catalyzed oxidation of 1,1′-bishydroxyl-methyl ferrocene—pH, temperature, substrate concentration, laccase quantity and surfactant were investigated further.
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Foundation item: Supported by the National Natural Science Foundation of China (39170203)
Biography: Ji Li-cai(1945-), male, professor, research direction: organic chemistry and biochemistry
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Li-cai, J., Pei-zhi, H., Chang-hua, J. et al. Study on laccase-catalyzed oxidation of disubstituted ferrocene and π-arene-π-cyclopentadienyliron derivatives. Wuhan Univ. J. Nat. Sci. 5, 351–356 (2000). https://doi.org/10.1007/BF02830155
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DOI: https://doi.org/10.1007/BF02830155