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Si-O and P-O motifs in inorganic rings and clusters

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Abstract

This article presents a brief overview of different kinds of silanols and the important reactions of N-bonded silanetriols. The synthesis and characterization of silanediols containing Si-N and Si-C bonds, (2,4,6-Me3C6H2)N(SiMe3)Si(Me)(OH)2 (1e) is described. 1e shows a polymeric crinkled tape type of structure due to extensive intermolecular hydrogen bonding. We also describe the formation of a neutral copper(II) complex derived from the reaction of CuCl2 with (O)P(3,5-Me2Pz)3 where the ligand undergoes a facile P-N bond cleavage and functions as an N2O type of tridentate ligand.

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Authors and Affiliations

  1. Department of Chemistry, Indian Institute of Technology, 208 016, Kanpur, India

    V. Chandrasekhar, S. Nagendran, S. Kingsley, V. Krishnan & R. Boomishankar

Authors
  1. V. Chandrasekhar
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  2. S. Nagendran
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  3. S. Kingsley
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  4. V. Krishnan
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  5. R. Boomishankar
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Correspondence to V. Chandrasekhar.

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Chandrasekhar, V., Nagendran, S., Kingsley, S. et al. Si-O and P-O motifs in inorganic rings and clusters. J Chem Sci 112, 171–178 (2000). https://doi.org/10.1007/BF02706169

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