Abstract
We investigate the photo- and roentgenoluminescence of ZnSe polycrystals obtained by the method of a self-propagating high-temperature synthesis (SHS). We establish an identity between the spectra of stationary luminescence of the polycrystals investigated and ZnSe single crystals. We show that the long-wave radiation of SHS crystals is due in the main to the presence of uncontrolled oxygen impurities in the crystals as well as to intrinsic defects that form donor-acceptor centers of self-activated luminescence. Investigations of roentgenoluminescence in the mode of its pulse excitation make it possible to isolate short-lived (550, 495, and 452 nm) and long-lived (580 and 630 nm) components of the radiation spectrum. The transformation of the corresponding spectra on a change in the temperature of the crystals is shown. The results demonstrate the possibility of using zinc selenide polycrystals produced by the SHS method in applied luminescence.
Similar content being viewed by others
References
D.D. Nedeoglo and A. V. Simashkevich, Electrical and Luminescence Properties of Zinc Selenide [in Russian], Kishinev (1984).
N. N. Korneva, Yu. F. Vaksman, and V. V. Serdyuk, Zh. Prikl. Spektrosk.,32, 294–298 (1980)
V. V. Serdyuk, N. N. Korneva, and Yu. F. Vaksman, Phys. Stat. Sol. (a),91, 173–183 (1985).
A. G. Merzhanov, in: Self-Propagating High-Temperature Synthesis. Physical Chemistry. Present-day Problems [in Russian], Moscow (1983), pp. 6–45.
S. V. Kozitskii, D. D. Polishchuk, V. P. Pisarskii, et al., Izv. Akad. Nauk SSSR, Neorg. Mater.,27, 2516–2519 (1991).
I. A. Naser, Yu. F. Vaksman, and V. V. Serdyuk, Zh. Prikl. Spektrosk.42, 659–662 (1985).
Yu. F. Vaksman, Fiz. Tekh. Poluprovodn.,29, 346–348 (1995).
S. V. Zubrits'kii and S. V. Kozits'kii, Ukr. Fizich. Zh.,37, 1665–1669 (1992).
H. Nelkovski and O. Phutsenventer, J. Luminesc.,17, 419–423 (1978).
A. Katsuhiro, M. Takao, and M. Yoshifumi, Phys. Rev. B,39, 3138–3144 (1989).
Yu. F. Vaksman, N. V. Malushin, V. M. Skobeeva, M. S. Aligera, and V. V. Serdyuk, Zh. Prikl Spektrosk.,21, 342–344 (1974).
A. L. Gurskii, E. V. Lutsenko, N. K. Morozova, and G. P. Yablonskii, Fiz. Tvyord. Tela,34, 3530–3536 (1992).
S. V. Kozitskii, Zh. Prikl. Spektrosk.,63, 124–128 (1996).
Author information
Authors and Affiliations
Additional information
Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 64, No. 3, pp. 333–337, May–June, 1997.
Rights and permissions
About this article
Cite this article
Kozitskii, S.V., Vaksman, Y.F. Luminescence of zinc selenide obtained by the method of self-propagating high-temperature synthesis. J Appl Spectrosc 64, 345–349 (1997). https://doi.org/10.1007/BF02675096
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF02675096