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Measurement and calculation of the ideal detonation velocity for liquid nitrocompounds

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Combustion, Explosion and Shock Waves Aims and scope

Abstract

Results of experimental measurements are presented for the dependence of the detonation velocity on the charge diameter for homogeneous nitromethane and propylene glycol dinitrate and for the ideal detonation velocities for allyl nitrate, diethlyene glycol dinitrate, methylene glycol dinitrate, and ethyl nitrate. Literature data on measurement of the dependence of the detonation velocity on the charge diameter for liquid TNT, nitroglycerin, glycol dinitrate, and methyl nitrate are collected. It is shown that measured values of the ideal detonation velocity are in good agreement with calculated values obtained by the SD method, which uses the equation of state of materials at a high pressure (see B. N. Kondrikov and A. I. Sumin, Fiz. Goreniya Vzryva, No. 1, 1987). A correlation between the ratio of the critical detonation velocity to the ideal velocity and the heat of explosion is obtained, which makes it possible to estimate the limiting value of the latter at which homogeneous liquid nitrocompounds lose detonatability.

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References

  1. B. N. Kondrikov, G. D. Kozak, V. B. Oblomskii, and A. V. Savkin, “Detonation transformations in aerated liquids,”Fiz. Goreniya Vzryva,23, No. 2, 83 (1987).

    Google Scholar 

  2. A. W. Campbell and R. Engelke, “The diameter effect in high-density heterogeneous explosives,” in:Proc. Sixth Symp (Int.) on Detonation, California (1976), pp. 642–652.

  3. B. N. Kondrikov and A. I. Sumin, “Equations of state for gases at high pressure,”Fiz. Goreniya Vzryva,23, No. 1, 114–122 (1987).

    ADS  Google Scholar 

  4. B. N. Kondrikov, G. D. Kozak, V. M. Raikova, and A. V. Starshinov, “Nitromethane detonation,”Dokl. Akad. Nauk SSSR,233, No. 3, 402–405 (1977).

    Google Scholar 

  5. A. W. Campbell, M. E. Malin, and T. E. Holland, “Detonation in heterogeneous explosives,” in:Proc. Second ONR Symp. on Detonation, Maryland (1955), pp. 336–359.

  6. E. Yu. Orlova, V. F. Zhilin, V. L. Zbarskii, and G. M. Shutov,Handbook for Laboratory Course on Nitrocompound Production [in Russian], Mendeleev Chem. Eng. Inst., Moscow (1969).

    Google Scholar 

  7. G. D. Kozak, B. N. Kondrikov, and A. V. Starshinov, “Critical detonation diameters of nitroesters,” in:Chemical Physics of Condensed Explosive Systems: Trans. Mendeleev Chem. Eng. Inst., No. 104, Moscow (1979), pp. 87–91.

  8. E. A. Igel and L. B. Seely, Jr., “The detonation behavior of liquid TNT,” in:Proc. Second ONR Symp. on Detonation, Maryland (1955), pp. 321–335.

  9. A. F. Belyaev,Combustion, Detonation, and Work of Explosions of Condensed Systems [in Russian], Nauka, Moscow (1968).

    Google Scholar 

  10. A. F. Belyaev, V. M. Karasev, and L. N. Azbukina, “Detonation velocity of nitroglycerin,” in:Physics of Explosions No. 5b [in Russian], Izd. Akad. Nauk SSSR, Moscow (1956), p. 97.

    Google Scholar 

  11. R. Kh. Kurbangallina, On the detonation of liquid explosives near the limiting diameter,” Candidate’s Dissertation in Tech, sci. Inst. of Chem. Phys., Acad. Sci. of the USSR, Moscow (1947).

    Google Scholar 

  12. S. B. Ratner and Yu. B. Khariton, “On the detonation velocities of nitroglycerin and glycol dinitrate,”Dokl. Akad. Nauk SSSR,41, No. 7, 307 (1943).

    Google Scholar 

  13. M. Kusakabe and S. Fujiware, “Explosive behavior of methylnitrate and its mixtures with liquid diluents,” in:Proc. Fifth Symp. on Detonation, USA (1970), p. 203.

  14. V. M. Raikova,Limiting Conditions of Combustion and Detonation of Nitroesters and Mixtures Based on Them, Candidate’s Dissertation in Phys.-Math. Sci., Mendeleev Chem. Eng. Inst., Moscow (1977).

    Google Scholar 

  15. B. N. Kondrikov and V. M. Raikova, “Detonation limits of explosive solutions,”Fiz. Goreniya Vzryva,13, No. 1, 55 (1977).

    Google Scholar 

  16. G. D. Kozak, B. N. Kondrikov, and V. V. Kondrat’ev, “On the effects of additives on the critical detonation diameter of nitroesters,”Fiz. Goreniya Vzryva,19, No. 4, 139 (1983).

    Google Scholar 

  17. G. D. Kozak, B. N. Kondrikov, and V. B. Oblomskii, “Spinning detonation in solids,”Fiz. Goreniya Vzryva,25, No. 4, 86 (1989).

    Google Scholar 

  18. V. N. Gamezo, “Kinetics of heat release in reaction zones of detonation waves,” Candidate’s Dissertation in Phys.-Math. Sci., Mendeleev Chem. Eng. Inst., Moscow (1992).

    Google Scholar 

  19. V. N. Gamezo, B. N. Kondrikov, and G. D. Kozak, “On the dependence of the critical detonation diameter of nitroesters on initial temperature,”Khim. Fiz.,12, No. 5, 719–722 (1993).

    Google Scholar 

  20. G. D. Kozak, B. N. Kondrikov, M. Yu. Eliseenkov, and Yu. S. Zhuk, “On the effect of viscosity on the detonation stability of diethylene glycol dinitrate,”Fiz. Goreniya Vzryva,32, No. 1, 111–114 (1966).

    Google Scholar 

  21. A. N. Dremin, S. D. Savrov, V. S. Trofimov, and K. K. Shvedov,Detonation Waves in Condensed Media [in Russian], Nauka, Moscow (1970).

    Google Scholar 

  22. V. N. Zamezo, G. V. Kozak, B. N. Kondrikov, and S. M. Khoroshev, “Detonation of mixtures of aromatic nitrocompounds with fuming sulfuric acid,” in:Explosive Materials and Pyrotechnics [in Russian], No. 3(218), 3–9 (1992).

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  1. Mendeleev Russian Chemical Engineering University, 125047, Moscow

    G. D. Kozak

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Translated fromFizika Goreniya i Vzryva, Vol. 34, No. 5, pp. 111–117, September–October 1998.

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Kozak, G.D. Measurement and calculation of the ideal detonation velocity for liquid nitrocompounds. Combust Explos Shock Waves 34, 581–586 (1998). https://doi.org/10.1007/BF02672682

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